Technology Process of C35H48N2O12
There total 7 articles about C35H48N2O12 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C47H72N2O14Si;
With
2,6-dimethylpyridine; t-butyldimethylsiyl triflate;
In
dichloromethane;
at 20 ℃;
for 3h;
In
methanol;
at 20 ℃;
for 40h;
Further stages.;
DOI:10.1002/anie.200603179
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 91 percent / CeCl3*7H2O; oxalic acid / acetonitrile / 2 h / 20 °C
2.1: oxalyl chloride; dimethylsulfoxide; triethylamine / CH2Cl2 / -60 - 20 °C
3.1: 74 percent / CH3MgCl / tetrahydrofuran; CH2Cl2 / 20 °C
4.1: 88 percent / DIPEA / CHCl3 / 6 h / 20 - 60 °C
5.1: 2,6-lutidine; tert-butyldimethylsilyl triflate / CH2Cl2 / 3 h / 20 °C
5.2: 86 percent / KF monohydrate / methanol / 40 h / 20 °C
With
2,6-dimethylpyridine; cerium(III) chloride; oxalyl dichloride; t-butyldimethylsiyl triflate; methylmagnesium chloride; oxalic acid; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; dichloromethane; chloroform; acetonitrile;
2.1: Swern oxidation;
DOI:10.1002/anie.200603179
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 88 percent / DIPEA / CHCl3 / 6 h / 20 - 60 °C
2.1: 2,6-lutidine; tert-butyldimethylsilyl triflate / CH2Cl2 / 3 h / 20 °C
2.2: 86 percent / KF monohydrate / methanol / 40 h / 20 °C
With
2,6-dimethylpyridine; t-butyldimethylsiyl triflate; N-ethyl-N,N-diisopropylamine;
In
dichloromethane; chloroform;
DOI:10.1002/anie.200603179
