(Z)-triethyl(1,2-diphenylethenyl)germane

Base Information

• Chemical Name: (Z)-triethyl(1,2-diphenylethenyl)germane
• CAS No.: 869795-36-8
• Molecular Formula: C₂₀H₂₆Ge
• Molecular Weight: 339.016
• Mol file: 869795-36-8.mol

Synonyms:(Z)-triethyl(1,2-diphenylethenyl)germane

Chemical Property of (Z)-triethyl(1,2-diphenylethenyl)germane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (Z)-triethyl(1,2-diphenylethenyl)germane

There total 2 articles about (Z)-triethyl(1,2-diphenylethenyl)germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

Triethylgerman (1188-14-3) + diphenyl acetylene (501-65-5) → (Z)-triethyl(1,2-diphenylethenyl)germane (869795-36-8)

Guidance literature:

dicarbonyl(cyclopentadienyl)methyliron(II); In neat (no solvent); mixt. of PhC2Ph (0.74 mmol), Et3GeH (0.89 mmol) and CpFe(CO)2Me (7 mol %) stirred under N2 (80°C, 18 h);

DOI:10.1039/c1cc12530c

Reference yield: 95.0%

cyclohexa-2,5-dien-1-yltriethylgermane + diphenyl acetylene (501-65-5) → (Z)-triethyl(1,2-diphenylethenyl)germane (869795-36-8)

Guidance literature:

With tris(pentafluorophenyl)borate; at 20 ℃; for 3h; diastereoselective reaction; Glovebox;

DOI:10.1021/acs.orglett.7b00672

upstream raw materials:

Triethylgerman

diphenyl acetylene