5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside
CAS No.:866823-12-3
Molecular Formula:C₂₅H₃₂F₃NO₈S
Molecular Weight:563.592
Hs Code.:

Synonyms:5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside

There total 1 articles about 5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 7139-63-1
1,3,4,6-tetra-O-acetyl-2-(trifluoroacetamido)-2-deoxy-β-D-glucopyranoside

: 7340-90-1
2-methyl-5-tert-butylthiophenol

: 866823-12-3
5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/jo900016j

Reference yield: 78.0%

: 866823-12-3
5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside

: O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->2)-O-(3,4,6-tri-O-acetyl-α-D-mannopyranosyl)-(1->3)-O-(2-O-acetyl-6-O-(chloroacetyl)-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosylazide

: O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->2)-O-(3,4,6-tri-O-acetyl-α-D-mannopyranosyl)-(1->3)-[O-(3,4,6-tri-O-acetyl-2-deoxy-2-trifluoroacetamido-β-D-glucopyranosyl)-(1->4)]-O-(2-O-acetyl-6-O-(chloroacetyl)-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosylazide

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane; at -30 ℃; for 2h; Inert atmosphere; Molecular sieve;
DOI:10.1021/jo900016j

Reference yield: 77.0%

: 866823-12-3
5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside

: C₉₈H₉₉ClN₆O₃₇

: C₁₁₂H₁₁₅ClF₃N₇O₄₅

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; In dichloromethane; at -40 ℃;
DOI:10.1016/j.tetlet.2005.04.061