1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol

Base Information

Chemical Name:1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol
CAS No.:156487-73-9
Molecular Formula:C₁₈H₂₆O₈
Molecular Weight:370.4
Hs Code.:

Synonyms:1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol

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Chemical Property of 1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol

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Technology Process of 1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol

There total 12 articles about 1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 156487-69-3
Methyl 4,6-O-benzylidene-2,3-bis-O-(methoxymethyl)-α-D-altropyranoside

: 156487-73-9
1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol

Guidance literature:: Multi-step reaction with 6 steps

1: 90 percent / NBS, BaCO₃ / CCl₄; various solvent(s) / 20 h / Heating

2: 96 percent / DBU / toluene / 20 h / 75 °C

3: (CF₃COO)2Hg / acetone; H₂O / 72 h / Ambient temperature

4: MsCl, Et₃N / CH₂Cl₂ / 0.5 h / Ambient temperature

5: BuLi / diethyl ether; hexane / 1.) -78 deg C, 1 h, 2.) -78 deg C, 1 h

6: MeONa / methanol / 1 h / Ambient temperature

With N-Bromosuccinimide; n-butyllithium; sodium methylate; mercury(II) trifluoroacetate; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; barium carbonate; In methanol; tetrachloromethane; diethyl ether; hexane; dichloromethane; water; acetone; toluene;
DOI:10.1039/a604365h

Reference yield:

: Benzoic acid (1S,2S,5R,6S)-2-(3,4-dimethoxy-phenyl)-2-hydroxy-5,6-bis-methoxymethoxy-cyclohex-3-enyl ester

: 156487-73-9
1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol

Guidance literature:: With sodium methylate; In methanol; for 1h; Yield given; Ambient temperature;
DOI:10.1039/a604365h

Reference yield:

: 156487-72-8
Benzoic acid (1S,5R,6S)-5,6-bis-methoxymethoxy-2-oxo-cyclohex-3-enyl ester

: 156487-73-9
1L-<1(OH),2,3/4>-3,4-Bis-O-(methoxymethyl)-1-(3,4-dimethoxyphenyl)cyclohex-5-ene-1,2,3,4-tetrol

Guidance literature:: Multi-step reaction with 2 steps

1: BuLi / diethyl ether; hexane / 1.) -78 deg C, 1 h, 2.) -78 deg C, 1 h

2: MeONa / methanol / 1 h / Ambient temperature

With n-butyllithium; sodium methylate; In methanol; diethyl ether; hexane;
DOI:10.1039/a604365h