Technology Process of trans-(C6F5)(Ph2P(CH2)2C(CH3)2(CH2)3CH=CH2)2Pt(CC)2H
There total 1 articles about trans-(C6F5)(Ph2P(CH2)2C(CH3)2(CH2)3CH=CH2)2Pt(CC)2H which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
HNEt2;
copper(l) iodide;
In
tetrahydrofuran; dichloromethane;
a Schlenk flask was charged with Pt-contg. compd. (0.323 mmol), CuI (0.065 mmol), CH2Cl2, and HNEt2, and cooled to -45°C; then H(CC)2H (5.17 mmol) in THF was added with stirring; cold bath was allowed to warm to 10°C for 3 h and removed; after an addnl. 2.5 h (orange supernatant/white ppt.), the solvent was removed by oil pump vac.; the residue was extd. with toluene; combined exts. were filtered through alumina column (toluene rinses); solvent was removed by oil pump vac.; elem. anal.;
- Guidance literature:
-
With
TMEDA; O2;
copper(l) chloride;
In
acetone;
a flask was charged with Pt-contg. compd. (0.264 mmol) and acetone; a Schlenk flask was charged with CuCl (0.51 mmol) and acetone, TMEDA was added with stirring during 0.5 h; O2 was bubbled through three-necked flask; heating to 65°C; after addn. of supernatant over 1.5 h and 0.5 h, the solvent was removedby rotary evapn. and oil pump vac.; toluene was added, and mixt. was tr ansferred to an alumina column; the column was eluted with toluene; the solvent was removed; elem. anal.;
