5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II)

Base Information

Chemical Name:5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II)
CAS No.:525600-90-2
Molecular Formula:C₃₇H₂₉BrN₄OZn
Molecular Weight:690.957
Hs Code.:

Synonyms:5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II)

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Chemical Property of 5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II)

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Technology Process of 5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II)

There total 1 articles about 5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 525600-88-8
5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethylporphinatozinc(II)

: 525600-90-2
5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II)

Guidance literature:: With basic alumina; air; 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; In toluene; soln. zinc chorin (toluene), basic alumina; 50°C; stirring under air; 66 h; concd.; solid dissolved (toluene); treated with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; stirred for 5 min; triethyamine; TaniguchiM. J. Org. Chem. 2002, 67, 7329-7342; TLC; concd. under reduced pressure; chromy. (silica, CH2Cl2);
DOI:10.1021/jp026941a

Reference yield: 54.0%

: 525600-90-2
5-(3-bromophenyl)-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II)

: 516493-24-6
N-(2,6-diisopropyl-4-ethynylphenyl)-9-(4-tert-butylphenyloxy)-3,4-perylenedicarboximide

: 525600-91-3
5-[3-[2-[4-[9-(4-tert-butylphenyloxy)perylene-3,4-dicarboximido]-3,5-diisopropylphenyl]ethynyl]phenyl]-17,18-dihydro-10-mesityl-18,18-dimethyl-17-oxoporphinatozinc(II)

Guidance literature:: With tri-o-tolylphosphine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In triethylamine; toluene; Br-substituted Zn oxochlorine, ethynyl-substituted perylene, Pd2(dba)3, P(o-tol)3 placed in flask filled with Ar; toluene/triethylamine added; mixt. heated to 60°C, stirring for 1h; Loewe, R. S.; et al. J. Mater. Chem. 2002, 12, 1530-1552.; cooled to 25°C; filtered; washed (CHCl3); filtrate concd. to afford solid; chromy (silica, CHCl3), preparative SEC (THF); chromy. (silicacolumn, CHCl3); washed MeOH;;
DOI:10.1021/jp026941a