Technology Process of N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d13)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide
There total 4 articles about N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d13)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
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352438-81-4
6,6,6,5,5,4,4,3,3,2,2,1,1-d13-hexylamine
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1430423-57-6
N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d13)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide
- Guidance literature:
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6,6,6,5,5,4,4,3,3,2,2,1,1-d13-hexylamine;
With
pyridine;
In
tetrahydrofuran; dichloromethane;
at 0 ℃;
for 1h;
Inert atmosphere;
benzene-1,2,4,5-tetracarbonyl chloride;
In
tetrahydrofuran; dichloromethane;
at 0 - 20 ℃;
for 25h;
Inert atmosphere;
DOI:10.1016/j.tetlet.2013.03.031
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1430423-57-6
N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d13)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide
- Guidance literature:
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Multi-step reaction with 3 steps
1.1: ammonium hydroxide / acetonitrile / 2 h / 0 - 20 °C
2.1: lithium aluminium deuteride / tetrahydrofuran / 12 h / 70 °C / Cooling; Inert atmosphere
3.1: pyridine / dichloromethane; tetrahydrofuran / 1 h / 0 °C / Inert atmosphere
3.2: 25 h / 0 - 20 °C / Inert atmosphere
With
pyridine; ammonium hydroxide; lithium aluminium deuteride;
In
tetrahydrofuran; dichloromethane; acetonitrile;
DOI:10.1016/j.tetlet.2013.03.031
-
-
1430423-57-6
N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d13)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide
- Guidance literature:
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Multi-step reaction with 5 steps
1.1: water-d2; 10% Pt/activated carbon; [D]-sodium hydroxide / 144 h / 220 °C
2.1: N,N-dimethyl-formamide; thionyl chloride / dichloromethane / 5 h / 50 °C
3.1: ammonium hydroxide / acetonitrile / 2 h / 0 - 20 °C
4.1: lithium aluminium deuteride / tetrahydrofuran / 12 h / 70 °C / Cooling; Inert atmosphere
5.1: pyridine / dichloromethane; tetrahydrofuran / 1 h / 0 °C / Inert atmosphere
5.2: 25 h / 0 - 20 °C / Inert atmosphere
With
pyridine; ammonium hydroxide; thionyl chloride; lithium aluminium deuteride; [D]-sodium hydroxide; 10% Pt/activated carbon; water-d2; N,N-dimethyl-formamide;
In
tetrahydrofuran; dichloromethane; acetonitrile;
DOI:10.1016/j.tetlet.2013.03.031
