N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d₁₃)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide

Base Information

• Chemical Name: N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d₁₃)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide
• CAS No.: 1430423-57-6
• Molecular Formula: C₃₄H₅₈N₄O₄
• Molecular Weight: 638.446
• Mol file: 1430423-57-6.mol

Synonyms:N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d₁₃)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide

Chemical Property of N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d₁₃)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d₁₃)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide

There total 4 articles about N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d₁₃)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

benzene-1,2,4,5-tetracarbonyl chloride (7710-20-5) + 6,6,6,5,5,4,4,3,3,2,2,1,1-d13-hexylamine (352438-81-4) → N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d13)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide (1430423-57-6)

Guidance literature:

6,6,6,5,5,4,4,3,3,2,2,1,1-d₁₃-hexylamine; With pyridine; In tetrahydrofuran; dichloromethane; at 0 ℃; for 1h; Inert atmosphere;

benzene-1,2,4,5-tetracarbonyl chloride; In tetrahydrofuran; dichloromethane; at 0 - 20 ℃; for 25h; Inert atmosphere;

DOI:10.1016/j.tetlet.2013.03.031

Reference yield:

C6(2)H11ClO → N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d13)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide (1430423-57-6)

Guidance literature:

Multi-step reaction with 3 steps

1.1: ammonium hydroxide / acetonitrile / 2 h / 0 - 20 °C

2.1: lithium aluminium deuteride / tetrahydrofuran / 12 h / 70 °C / Cooling; Inert atmosphere

3.1: pyridine / dichloromethane; tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

3.2: 25 h / 0 - 20 °C / Inert atmosphere

With pyridine; ammonium hydroxide; lithium aluminium deuteride; In tetrahydrofuran; dichloromethane; acetonitrile;

DOI:10.1016/j.tetlet.2013.03.031

Reference yield:

hexanoic acid (142-62-1) → N,N’,N’’,N’’’-((6,6,6,5,5,4,4,3,3,2,2,1,1-d13)-tetrahexyl)benzene-1,2,4,5-tetracarboxamide (1430423-57-6)

Guidance literature:

Multi-step reaction with 5 steps

1.1: water-d2; 10% Pt/activated carbon; [D]-sodium hydroxide / 144 h / 220 °C

2.1: N,N-dimethyl-formamide; thionyl chloride / dichloromethane / 5 h / 50 °C

3.1: ammonium hydroxide / acetonitrile / 2 h / 0 - 20 °C

4.1: lithium aluminium deuteride / tetrahydrofuran / 12 h / 70 °C / Cooling; Inert atmosphere

5.1: pyridine / dichloromethane; tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

5.2: 25 h / 0 - 20 °C / Inert atmosphere

With pyridine; ammonium hydroxide; thionyl chloride; lithium aluminium deuteride; [D]-sodium hydroxide; 10% Pt/activated carbon; water-d2; N,N-dimethyl-formamide; In tetrahydrofuran; dichloromethane; acetonitrile;

DOI:10.1016/j.tetlet.2013.03.031

upstream raw materials:

benzene-1,2,4,5-tetracarbonyl chloride

6,6,6,5,5,4,4,3,3,2,2,1,1-d₁₃-hexylamine

hexanoic acid

6,6,6,5,5,4,4,3,3,2,2-d₁₁-hexanoic acid

Refernces