(1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol

Base Information

Chemical Name:(1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol
CAS No.:514204-97-8
Molecular Formula:C₁₇H₃₂O₃Si
Molecular Weight:312.525
Hs Code.:

Synonyms:(1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol

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Chemical Property of (1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol

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Technology Process of (1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol

There total 1 articles about (1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 107-30-2
chloromethyl methyl ether

: (1R,6S)-6-(((2,3-dimethylbutan-2-yl)dimethylsilyl)oxy)-2-methylcyclohexa-2,4-dienol

: 514204-97-8
(1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 - 20 ℃; for 20h;
DOI:10.1016/S0957-4166(02)00682-1

Reference yield: 52.0%

: 514204-97-8
(1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol

: 514204-98-9
(1S,2S,3S,4S)-4-(dimethylthexylsilyl)oxy-3-O-methoxymethyl-2-methyl-5-cyclohexen-1,2,3-triol

Guidance literature:: With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In water; acetone; at 20 ℃; for 6h;
DOI:10.1016/S0957-4166(02)00682-1

Reference yield:

: 514204-97-8
(1S,2R)-1-(dimethylthexylsilyl)oxy-2-O-methoxymethyl-3-methyl-3,5-cyclohexadien-2-ol

: 514205-01-7
(2R,3S,4S)-4-(dimethylthexylsilyl)oxy-3-O-methoxymethyl-2,3-dihydroxy-2-methyl-5-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / N-methylmorpholine-N-oxide; OsO₄ / acetone; H₂O / 6 h / 20 °C

2: 80 percent / Dess-Martin reagent / CH₂Cl₂ / 20 °C

With osmium(VIII) oxide; Dess-Martin periodane; 4-methylmorpholine N-oxide; In dichloromethane; water; acetone; 2: Dess-Martin oxidation;
DOI:10.1016/S0957-4166(02)00682-1