1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

Base Information

Chemical Name:1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione
CAS No.:174290-95-0
Molecular Formula:C₄₉H₅₂N₄O₉Si
Molecular Weight:869.059
Hs Code.:

1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

Synonyms:1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

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Chemical Property of 1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

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Technology Process of 1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

There total 3 articles about 1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 174290-94-9
1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-6-O-(4-methoxybenzyl)-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

: 174290-95-0
1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

Guidance literature:: With water; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; Ambient temperature;
DOI:10.1021/ja952907g

Reference yield:

: 174290-92-7
1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-6-O-(4-methoxybenzyl)-2-O-<(pentafluorophenoxy)thiocarbonyl>-α-D-altropyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dion

: 174290-95-0
1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 74 percent / n-Bu₃SnH, AIBN / benzene / 2 h / Heating

2: 97 percent / DDQ, H₂O / CH₂Cl₂ / Ambient temperature

With 2,2'-azobis(isobutyronitrile); water; tri-n-butyl-tin hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; benzene;
DOI:10.1021/ja952907g

Reference yield:

: 1-Benzyloxymethyl-3-{1-[(3aS,4R,7aS)-1-benzyloxymethyl-7-hydroxy-4-(4-methoxy-benzyloxymethyl)-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-yl]-1H-indol-3-yl}-4-[1-(2-trimethylsilanyl-ethoxymethyl)-1H-indol-3-yl]-pyrrole-2,5-dione

: 174290-95-0
1-<(benzyloxy)methyl>-3,4-dihydro-4-(<3-<<(benzyloxy)methyl>amino>-3-N,4-O-carbonyl-2-deoxy-α-D-allopyranosyl>-1H-indol-3-yl)-3-(1-<2-(trimethylsilyl)ethoxymethyl>-1H-indol-3-yl)-1H-pyrrole-2,5-dione

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) DMAP, Py / 1.) CH₂Cl₂, reflux, 4 h, 2.) CH₂Cl₂, reflux, 4 h

2: 74 percent / n-Bu₃SnH, AIBN / benzene / 2 h / Heating

3: 97 percent / DDQ, H₂O / CH₂Cl₂ / Ambient temperature

With pyridine; dmap; 2,2'-azobis(isobutyronitrile); water; tri-n-butyl-tin hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; benzene;
DOI:10.1021/ja952907g