Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Base Information

Chemical Name:Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)
CAS No.:97921-20-5
Molecular Formula:C₃₃H₅₂NiO₂P₂
Molecular Weight:601.412
Hs Code.:

Ni(C<sub>6</sub>H<sub>4</sub>CO<sub>2</sub>)((C<sub>6</sub>H<sub>11</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>11</sub>)2)

Synonyms:Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Suppliers and Price of Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

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Technology Process of Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

There total 2 articles about Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 114907-51-6
[η²-benzyne][1,2-bis(dicyclohexylphosphino)ethane]nickel(0)

: 97921-20-5
Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: With carbon dioxide; In tetrahydrofuran; Ni-complex was put under an atmosphere of CO2 in Schlenk tube, CO2-satd. THF was injected, mixt. was stirred until absorption of CO2 ceased (2 min); soln. was dild. gradually with hexane, resulting crystals collected; elem. anal.;

Reference yield:

: 97921-23-8
NiBr(C₆H₄Br)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

: 97921-20-5
Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: Multi-step reaction with 3 steps

1: LiCl; THF / tetrahydrofuran; methanol

2: Na#Hg / tetrahydrofuran

3: carbon dioxide / tetrahydrofuran

With LiCl; THF; Na#Hg; carbon dioxide; In tetrahydrofuran; methanol;

Reference yield: 95.0%

: 97921-20-5
Ni(C₆H₄CO₂)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

: 76-05-1
trifluoroacetic acid

: 97921-11-4
Ni(O₂CCF₃)2((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

: 65-85-0,8013-63-6
benzoic acid

Guidance literature:: In dichloromethane; Ni-complex in dry CH2Cl2 was treated dropwise under N2 with CF3COOH (2 equiv); evapd., washed with dry ether, recrystd. from CH2Cl2/hexane to give bis(trifluoroacetate) complex (identified by its (31)P NMR spectrum), etherext. was evapd. to dryness, sublimed at 65°C/0.01 mm to give PhCOOH (identified by m.p.);