FeRhP(C₆H₅)2(P(C₂H₅)3)2(CO)4

Base Information

• Chemical Name: FeRhP(C₆H₅)2(P(C₂H₅)3)2(CO)4
• CAS No.: 82135-57-7
• Molecular Formula: C₂₈H₄₀FeO₄P₃Rh
• Molecular Weight: 692.297
• Mol file: 82135-57-7.mol

Synonyms:FeRhP(C₆H₅)2(P(C₂H₅)3)2(CO)4

Chemical Property of FeRhP(C₆H₅)2(P(C₂H₅)3)2(CO)4

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of FeRhP(C₆H₅)2(P(C₂H₅)3)2(CO)4

There total 3 articles about FeRhP(C₆H₅)2(P(C₂H₅)3)2(CO)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

Fe(CO)4(PH(C6H5)2) (18399-66-1,38967-68-9) + trans-ClRh(CO)(PEt3)2 (14871-47-7,15631-52-4) → FeRhP(C6H5)2(P(C2H5)3)2(CO)4 (82135-57-7)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; byproducts: LiCl; n-BuLi was added to a THF soln. of Fe-complex, the soln. was slowly added to a THF soln. of Rh-complex, the soln. was stired for 2-5 h at 25°C;; extd. with toluene, chromd. on alumina with CH2Cl2-hexane under N2;;

Reference yield: 64.0%

trans-ClRh(CO)(PEt3)2 (14871-47-7,15631-52-4) + Li[PPh2Fe(CO)4] (82042-06-6) → FeRhP(C6H5)2(P(C2H5)3)2(CO)4 (82135-57-7)

Guidance literature:

In tetrahydrofuran; THF soln. of Fe complex was slowly added under N2 to soln. of Rh complex in THF; stirring at 23°C for 3 h; evapn., extn. with toluene, exts. were filtered and concd.; chromy. on alumina (CH2Cl2/hexane) under N2; elem. anal.;

Reference yield:

FeRhP(C6H5)2(P(C2H5)3)2(CO)5 (81987-90-8) → FeRhP(C6H5)2(P(C2H5)3)2(CO)4 (82135-57-7)

Guidance literature:

byproducts: CO;

upstream raw materials:

FeRhP(C₆H₅)2(P(C₂H₅)3)2(CO)5

trans-ClRh(CO)(PEt₃)2

Li[PPh₂Fe(CO)4]

Fe(CO)4(PH(C₆H₅)2)

Downstream raw materials:

FeRhP(C₆H₅)2(P(C₂H₅)3)2(CO)5