2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

Base Information

Chemical Name:2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine
CAS No.:419536-89-3
Molecular Formula:C₁₈H₂₆OSi
Molecular Weight:286.489
Hs Code.:

Synonyms:2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

Suppliers and Price of 2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

There total 1 articles about 2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: allyl-dimethyl-[3-methyl-1-(2-methyl-allyl)-1-phenyl-but-3-enyloxy]-silane

: (S)-2,2,5-Trimethyl-7-(2-methyl-allyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

: 419536-89-3
2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

Guidance literature:: With biphenol-based chiral Mo; In benzene; for 2h; Title compound not separated from byproducts;

Reference yield: 90.0%

: 917-54-4
methyllithium

: 419536-89-3
2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

: 419537-06-7
2,6-dimethyl-4-phenyl-8-(trimethyl-silanyl)-octa-1,6-dien-4-ol

Guidance literature:: In tetrahydrofuran; at 22 ℃; for 24h;
DOI:10.1021/ja012679s

Reference yield:

: 419536-89-3
2,2,5-trimethyl-7-(2-methylallyl)-7-phenyl-2,3,6,7-tetrahydro-[1,2]oxasilepine

: 3,7-dimethyl-5-phenyl-octa-1,7-diene-3,5-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / tetrahydrofuran / 24 h / 22 °C

2: 36 percent / m-CPBA; NaHCO₃ / CH₂Cl₂ / 4 h / -30 °C

3: 86 percent / n-Bu₄NF / tetrahydrofuran / 0.25 h / 0 °C

With tetrabutyl ammonium fluoride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja012679s