7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol

Base Information

Chemical Name:7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol
CAS No.:365414-57-9
Molecular Formula:C₃₀H₄₇O₄PSi
Molecular Weight:530.76
Hs Code.:

Synonyms:7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol

Suppliers and Price of 7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol

There total 3 articles about 7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 4455-77-0
(methoxymethyl)diphenylphosphine oxide

: 365414-56-8
10-(tert-butyldimethylsilyloxy)-1-decen-5-one

: 365414-57-9
7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 3h;
DOI:10.1021/jo034853w

Reference yield:

: 161232-10-6
6-(tert-butyl-dimethylsilanoxy)hexanoic acid methyl ester

: 365414-57-9
7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol

Guidance literature:: Multi-step reaction with 3 steps

1.1: AlMe₃ / benzene; toluene / 1 h / 0 - 20 °C

1.2: 61 percent / benzene; toluene / 12 h / 20 °C

2.1: 85 percent / tetrahydrofuran / 1 h / 0 °C

3.1: 92 percent / LDA / tetrahydrofuran / 3 h / -78 °C

With trimethylaluminum; lithium diisopropyl amide; In tetrahydrofuran; toluene; benzene;
DOI:10.1021/jo034853w

Reference yield:

: 365414-63-7
6-(O-tert-butyldimethylsilyl)hexanoic acid N-methoxy-N-methylamide

: 365414-57-9
7-(tert-butyldimethylsilyloxy)-1-diphenylphosphinyl-1-methoxy-2-(3-butenyl)-2-heptanol

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / tetrahydrofuran / 1 h / 0 °C

2: 92 percent / LDA / tetrahydrofuran / 3 h / -78 °C

With lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1021/jo034853w