<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester

Base Information

Chemical Name:<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester
CAS No.:149079-65-2
Molecular Formula:C₁₆H₂₀O₄
Molecular Weight:276.332
Hs Code.:

Synonyms:<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester

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Chemical Property of <1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester

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Technology Process of <1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester

There total 5 articles about <1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 19312-06-2
4,5-dihydro-4,4-dimethyl-2-phenoxazole

: 149079-65-2
<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi / 1.) THF, hexane, -45 deg C, 3.5 h, 2.) THF, hexane, a) -45 deg C, 1 h, b) 25 deg C, 15 h

2: 5 percent aq. oxalic acid / 75 h / Ambient temperature

3: H₂ / 20percent Pd(OH)2-C / acetic acid / 96 h / 760 Torr / Ambient temperature

4: HCl / 16 h / 25 °C

With hydrogenchloride; n-butyllithium; hydrogen; oxalic acid; palladium hydroxide - carbon; In acetic acid;
DOI:10.1021/jm00062a013

Reference yield:

: 404575-34-4
7-oxabicyclo<2.2.1>heptane tetrahydrofuranol

: 149079-65-2
<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi / 1.) THF, hexane, -45 deg C, 3.5 h, 2.) THF, hexane, a) -45 deg C, 1 h, b) 25 deg C, 15 h

2: 5 percent aq. oxalic acid / 75 h / Ambient temperature

3: H₂ / 20percent Pd(OH)2-C / acetic acid / 96 h / 760 Torr / Ambient temperature

4: HCl / 16 h / 25 °C

With hydrogenchloride; n-butyllithium; hydrogen; oxalic acid; palladium hydroxide - carbon; In acetic acid;
DOI:10.1021/jm00062a013

Reference yield:

: 3-((1S,2R,3R,4R)-3-Hydroxymethyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-3H-isobenzofuran-1-one

: 149079-65-2
<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / 20percent Pd(OH)2-C / acetic acid / 96 h / 760 Torr / Ambient temperature

2: HCl / 16 h / 25 °C

With hydrogenchloride; hydrogen; palladium hydroxide - carbon; In acetic acid;
DOI:10.1021/jm00062a013