<4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

Base Information

Chemical Name:<4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane
CAS No.:152453-74-2
Molecular Formula:C₃₆H₄₈O₅Si
Molecular Weight:588.86
Hs Code.:

<4R-<4R*<S*(1R*,2S*)>>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

Synonyms:<4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

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Chemical Property of <4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

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Technology Process of <4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

There total 5 articles about <4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 152453-73-1
<4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol

: 152453-74-2
<4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 48h; Ambient temperature;
DOI:10.1021/ja00136a025

Reference yield:

: 67320-20-1,83692-41-5,94292-91-8,64722-95-8
1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-3,3-bis-ethylsulfanyl-propan-1-ol

: 152453-74-2
<4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) NaH / 1.) DMF, RT, 3 h, 2.) DMF, RT, 45 min

2: 77 percent / CaCO₃, HgCl₂ / acetonitrile; H₂O / 0.83 h / Ambient temperature

3: 1.) BF₃*Et₂O, 2.) a) 3 M aq. NaOH, b) 30percent aq. H₂O₂ / 1.) THF, hexane, -78 deg C, 1.5 h, 2.) THF, hexane, a) from -78 deg C to RT

4: 84 percent / imidazole / dimethylformamide / 48 h / Ambient temperature

With 1H-imidazole; sodium hydroxide; boron trifluoride diethyl etherate; dihydrogen peroxide; sodium hydride; calcium carbonate; mercury dichloride; In water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ja00136a025

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 152453-74-2
<4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) NaH / 1.) DMF, RT, 3 h, 2.) DMF, RT, 45 min

2: 77 percent / CaCO₃, HgCl₂ / acetonitrile; H₂O / 0.83 h / Ambient temperature

3: 1.) BF₃*Et₂O, 2.) a) 3 M aq. NaOH, b) 30percent aq. H₂O₂ / 1.) THF, hexane, -78 deg C, 1.5 h, 2.) THF, hexane, a) from -78 deg C to RT

4: 84 percent / imidazole / dimethylformamide / 48 h / Ambient temperature

With 1H-imidazole; sodium hydroxide; boron trifluoride diethyl etherate; dihydrogen peroxide; sodium hydride; calcium carbonate; mercury dichloride; In water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ja00136a025