(C₅H₄CH₃)Co(CO)[P(C₆H₅)3]

Base Information

• Chemical Name: (C₅H₄CH₃)Co(CO)[P(C₆H₅)3]
• CAS No.: 75297-01-7
• Molecular Formula: C₂₅H₂₂CoOP
• Molecular Weight: 428.416
• Mol file: 75297-01-7.mol

Synonyms:(C₅H₄CH₃)Co(CO)[P(C₆H₅)3]

Chemical Property of (C₅H₄CH₃)Co(CO)[P(C₆H₅)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅H₄CH₃)Co(CO)[P(C₆H₅)3]

There total 1 articles about (C₅H₄CH₃)Co(CO)[P(C₆H₅)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

dicarbonyl(η(5)-methylcyclopentadienyl)cobalt → (C5H4CH3)Co(CO)[P(C6H5)3] (75297-01-7)

Guidance literature:

With triphenylphosphine; In toluene; soln. of the Co-compound and PPh3 in toluene held at reflux for 16 h; solvent removed, oil redissolved in THF, filtered, solvent removed, dissolved in mixed hexanes, soln. cooled to -30°C, washed with cold hexanes, dried under vacuum, elem. anal.;

DOI:10.1021/ja00543a017

Reference yield: 90.0%

bromocyane (506-68-3) + (C5H4CH3)Co(CO)[P(C6H5)3] (75297-01-7) → (C5H4CH3)Co[P(C6H5)3](CN)Br (105202-89-9)

Guidance literature:

In diethyl ether; byproducts: CO; under N2; Co-complex in Et2O mixed with BrCN in Et2O, pptn. of dark green solid; elem. anal.;

DOI:10.1016/0022-328X(86)84013-X

Reference yield: 90.0%

cyanogen iodide (506-78-5) + (C5H4CH3)Co(CO)[P(C6H5)3] (75297-01-7) → (C5H4CH3)Co[P(C6H5)3](CN)I (105202-90-2)

Guidance literature:

In diethyl ether; byproducts: CO; under N2; Co-complex in Et2O mixed with soln. of ICN in Et2O, pptn. of dark brown solid; elem. anal.;

DOI:10.1016/0022-328X(86)84013-X

Downstream raw materials:

(C₅H₄CH₃)Co[P(C₆H₅)3](CN)Br

(C₅H₄CH₃)Co[P(C₆H₅)3](CN)I

(CH₃C₅H₄)Co(C₂H₄)(P(C₆H₅)3)

C₅H₄CH₃^(1-)*Co⁽¹⁺⁾*P(C₆H₅)3*(NC)2CC(CN)2=(C₅H₄CH₃)Co[P(C₆H₅)3][(NC)2CC(CN)2]