1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide

Base Information

Chemical Name:1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide
CAS No.:1574561-77-5
Molecular Formula:C₁₅H₁₈N₂O₄S₂
Molecular Weight:354.451
Hs Code.:

Synonyms:1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide

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Chemical Property of 1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide

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Technology Process of 1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide

There total 7 articles about 1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 3-(4-methoxyphenyl)-6,8-dimethyl-2-[(phenylmethoxy)methyl]-4 methylhydroxy-2,4-dithia-6,8-diazabicyclo[3.2.2]nonane-7,9-dione

: 1574561-77-5
1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide

Guidance literature:: 3-(4-methoxyphenyl)-6,8-dimethyl-2-[(phenylmethoxy)methyl]-4 methylhydroxy-2,4-dithia-6,8-diazabicyclo[3.2.2]nonane-7,9-dione; With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 0.166667h;

With perchloric acid; dimethylsulfide; In methanol; dichloromethane; at 0 - 20 ℃; for 8h;

Reference yield:

: 21579-45-3
1,4-dimethyl-2,5-diketopiperazine-3,6-dibromide

: 1574561-77-5
1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide

Guidance literature:: Multi-step reaction with 7 steps

1.1: triethylamine / chloroform; acetone / 4 h / 4 °C

2.1: hydrogenchloride / diethyl ether; methanol / 2 h / Reflux

3.1: boron trifluoride diethyl etherate / dichloromethane / 16 h / 20 °C

4.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C

5.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C

6.1: boron trichloride / dichloromethane / 0.17 h / 0 °C

7.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.17 h / 0 °C

7.2: 8 h / 0 - 20 °C

With hydrogenchloride; n-butyllithium; boron trifluoride diethyl etherate; boron trichloride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; chloroform; acetone;

Reference yield:

: 1259033-17-4
3-(4-methoxyphenyl)-6,8-dimethyl-2-[(phenylmethoxy)methyl]-2,4-dithia-6,8-diazabicyclo[3.2.2]nonane-7,9-dione

: 1574561-77-5
1,4-dimethyl-2-methylhydroxy-5-[(phenylmethoxy)methyl]-2,5-piperazinedione-3,6-disulfide

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C

2.1: boron trichloride / dichloromethane / 0.17 h / 0 °C

3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.17 h / 0 °C

3.2: 8 h / 0 - 20 °C

With n-butyllithium; boron trichloride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; dichloromethane;