C₁₆H₂₆O₃Si

Base Information

• Chemical Name: C₁₆H₂₆O₃Si
• CAS No.: 1265278-88-3
• Molecular Formula: C₁₆H₂₆O₃Si
• Molecular Weight: 294.466
• Mol file: 1265278-88-3.mol

Synonyms:C₁₆H₂₆O₃Si

Chemical Property of C₁₆H₂₆O₃Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₆H₂₆O₃Si

There total 3 articles about C₁₆H₂₆O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

C17H28O4Si (1265278-87-2) → C16H26O3Si (1265278-88-3)

Guidance literature:

With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 1.5h; Inert atmosphere;

DOI:10.1002/ejoc.201001281

Reference yield:

C17H26O4Si (1265278-86-1) → C16H26O3Si (1265278-88-3)

Guidance literature:

Multi-step reaction with 2 steps

1: palladium 10% on activated carbon; hydrogen / methanol / 0.5 h / 23 °C

2: diisobutylaluminium hydride / dichloromethane; toluene / 1.5 h / -78 °C / Inert atmosphere

With palladium 10% on activated carbon; hydrogen; diisobutylaluminium hydride; In methanol; dichloromethane; toluene;

DOI:10.1002/ejoc.201001281

Reference yield:

3-[(tert-butyldimethylsilyl)oxy]-2-methoxybenzaldehyde → C16H26O3Si (1265278-88-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: lithium bromide / tetrahydrofuran / 0.25 h / 23 °C / Inert atmosphere

1.2: 0.25 h / 23 °C / Inert atmosphere

1.3: 5 h / 23 °C / Inert atmosphere

2.1: palladium 10% on activated carbon; hydrogen / methanol / 0.5 h / 23 °C

3.1: diisobutylaluminium hydride / dichloromethane; toluene / 1.5 h / -78 °C / Inert atmosphere

With palladium 10% on activated carbon; hydrogen; diisobutylaluminium hydride; lithium bromide; In tetrahydrofuran; methanol; dichloromethane; toluene; 1.3: Wittig reaction;

DOI:10.1002/ejoc.201001281

upstream raw materials:

C₁₇H₂₆O₄Si

C₁₇H₂₈O₄Si

Downstream raw materials:

C₁₃H₁₈O₃

C₁₉H₃₂O₃Si