6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole

Base Information

Chemical Name:6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole
CAS No.:307943-45-9
Molecular Formula:C₄₂H₄₈F₅NO₇S
Molecular Weight:805.904
Hs Code.:

Synonyms:6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole

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Chemical Property of 6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole

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Technology Process of 6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole

There total 7 articles about 6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 307943-51-7
4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl bromide

: 307943-40-4
6,11-dihydro-3,8-bis(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole

: 307943-45-9
6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole

Guidance literature:: 6,11-dihydro-3,8-bis(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole; With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 0.5h;

4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl bromide; In N,N-dimethyl-formamide; for 2h;
DOI:10.1002/1521-4184(20009)333:9<305::AID-ARDP305>3.0.CO;2-Q

Reference yield:

: 6132-77-0
3-methoxy-8-methoxy-5,6-dihydrobenzo carbazole

: 307943-45-9
6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole

Guidance literature:: Multi-step reaction with 3 steps

1.1: 64 percent / BBr₃ / CH₂Cl₂ / 6 h / 20 - 50 °C

2.1: 45 percent / HCl / ethyl acetate / 3.5 h / 20 °C

3.1: NaH / dimethylformamide / 0.5 h / 0 °C

3.2: 51 percent / dimethylformamide / 2 h

With hydrogenchloride; boron tribromide; sodium hydride; In dichloromethane; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1002/1521-4184(20009)333:9<305::AID-ARDP305>3.0.CO;2-Q

Reference yield:

: 160598-75-4
1-(acetylsulfanyl)-4,4,5,5,5-pentafluoropentane

: 307943-45-9
6,11-dihydro-11-[4-[4-(4,4,5,5,5-pentafluoropentylsulfonyl)butoxy]benzyl]-3,8-di-(tetrahydropyran-2-yloxy)-5H-benzo[a]carbazole

Guidance literature:: Multi-step reaction with 6 steps

1.1: NaOMe / methanol / 0.5 h / 60 - 70 °C

2.1: NaH / dimethylformamide

2.2: 73 percent / dimethylformamide / 50 - 60 °C

3.1: 78 percent / LiAlH₄ / tetrahydrofuran; diethyl ether / 7 h / Heating

4.1: 68 percent / m-chloroperbenzoic acid / CHCl₃ / 20 °C

5.1: 54 percent / PBr₃ / CH₂Cl₂ / 0.5 h / 0 °C

6.1: NaH / dimethylformamide / 0.5 h / 0 °C

6.2: 51 percent / dimethylformamide / 2 h

With lithium aluminium tetrahydride; sodium methylate; phosphorus tribromide; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; chloroform; N,N-dimethyl-formamide;
DOI:10.1002/1521-4184(20009)333:9<305::AID-ARDP305>3.0.CO;2-Q