(S)-1-methylprop-2-enyl 4-methoxyphenyl ether

Base Information

• Chemical Name: (S)-1-methylprop-2-enyl 4-methoxyphenyl ether
• CAS No.: 101933-95-3
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 178.231
• Mol file: 101933-95-3.mol

Synonyms:(S)-1-methylprop-2-enyl 4-methoxyphenyl ether

Chemical Property of (S)-1-methylprop-2-enyl 4-methoxyphenyl ether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (S)-1-methylprop-2-enyl 4-methoxyphenyl ether

There total 5 articles about (S)-1-methylprop-2-enyl 4-methoxyphenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-crotyl methyl carbonate (103185-13-3) + 4-methoxy-phenol (150-76-5) → (R)-1-methylprop-2-enyl 4-methoxyphenyl ether + (S)-1-methylprop-2-enyl 4-methoxyphenyl ether (101933-95-3)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; Pd₂dba3-chiral cyclohexanediamine derivative; In chloroform; Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/ja981142k

Reference yield:

(E)-crotyl methyl carbonate (103185-13-3) + 4-methoxy-phenol (150-76-5) → 1-(but-1-en-2-yloxy)-4-methoxybenzene + (R)-1-methylprop-2-enyl 4-methoxyphenyl ether + (S)-1-methylprop-2-enyl 4-methoxyphenyl ether (101933-95-3)

Guidance literature:

With (R,R)-bis(o-PPh₂-benzamido)cyclohexane; Pd₂dba3-CH₃; In toluene;

DOI:10.1021/ja026438b

Reference yield:

(E)-but-2-en-1-yl-(4-methoxyphenyl) carbonate (1643966-03-3) → (R)-1-methylprop-2-enyl 4-methoxyphenyl ether + (S)-1-methylprop-2-enyl 4-methoxyphenyl ether (101933-95-3)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; In dichloromethane; at 0 ℃; for 4h; Temperature; Reagent/catalyst; Optical yield = 84 %ee; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejoc.201402326

upstream raw materials:

(E)-crotyl methyl carbonate

4-methoxy-phenol

(E)-but-2-en-1-yl-(4-methoxyphenyl) carbonate

Downstream raw materials:

5-[(S)-5-(4-methoxyphenoxy)hexyl-1-sulfonyl]-1-phenyl-1H-tetrazole

ethyl (E)-(S)-5-(4-methoxyphenoxy)-hex-2-enoate

(S)-5-(4-methoxyphenoxy)-hexan-1-ol

(S)-3-(4-methoxyphenoxy)-butan-1-ol