1-((2-ETHYLHEXYL)OXY)-4-METHOXYBENZENE

Base Information

• Chemical Name: 1-((2-ETHYLHEXYL)OXY)-4-METHOXYBENZENE
• CAS No.: 146370-51-6
• Molecular Formula: C15H24 O2
• Molecular Weight: 236.354
• Hs Code.: 2909309090
• DSSTox Substance ID: DTXSID10391618
• Nikkaji Number: J1.295.830G
• Mol file: 146370-51-6.mol

Synonyms:1-(2-Ethylhexyloxy)-4-methoxybenzene;1-Methoxy-4-(2-ethylhexyloxy)benzene; 4-(2-Ethylhexyloxy)-1-methoxybenzene;4-(2-Ethylhexyloxy)anisole

Chemical Property of 1-((2-ETHYLHEXYL)OXY)-4-METHOXYBENZENE

Chemical Property:

• Vapor Pressure: 0.000545mmHg at 25°C
• Refractive Index: n20/D 1.4960(lit.)
• Boiling Point: 303-304 °C(lit.)
• Flash Point: >230 °F
• PSA: 18.46000
• Density: 0.960 g/mL at 25 °C(lit.)
• LogP: 4.29040
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 8
• Exact Mass: 236.177630004
• Heavy Atom Count: 17
• Complexity: 174

Purity/Quality:

98.5% ^*data from raw suppliers

1-[(2-Ethylhexyl)oxy]-4-methoxybenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC(CC)COC1=CC=C(C=C1)OC
• Uses: 1-[(2-Ethylhexyl)oxy]-4-methoxybenzene [4-(2-Ethylheptyloxy)benzaldehyde] may be used in the preparation of 1,4-bis(bromomethyl)-2-((2′-ethylhexyl)oxy)-5-methoxybenzene and 1,4-dibromo-2-[(2-ethylhexyl)oxy]-5-methoxy-benzene.

Technology Process of 1-((2-ETHYLHEXYL)OXY)-4-METHOXYBENZENE

There total 2 articles about 1-((2-ETHYLHEXYL)OXY)-4-METHOXYBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

3-bromomethylheptane (18908-66-2) + 4-methoxy-phenol (150-76-5) → 1-((2-ethylhexyl)oxy)-4-methoxybenzene (146370-51-6)

Guidance literature:

With potassium tert-butylate; In N,N-dimethyl-formamide; at 50 - 65 ℃; for 6.25h;

DOI:10.1080/00397910802238775

Reference yield: 72.0%

2-Ethylhexyl alcohol (104-76-7) + para-iodoanisole (696-62-8) → 1-((2-ethylhexyl)oxy)-4-methoxybenzene (146370-51-6)

Guidance literature:

With caesium carbonate; copper(l) iodide; at 110 ℃; for 24h;

DOI:10.1016/j.tetlet.2008.03.015

Reference yield: 81.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1-((2-ethylhexyl)oxy)-4-methoxybenzene (146370-51-6) → α,α′-dibromo-2-methoxy-5-(2-ethylhexyloxy)xylene (209625-37-6)

Guidance literature:

With hydrogen bromide; acetic acid; at 70 ℃; for 4h; Inert atmosphere;

upstream raw materials:

3-bromomethylheptane

4-methoxy-phenol

2-Ethylhexyl alcohol

para-iodoanisole

Downstream raw materials:

α,α'-dichloro-p-<5-((2'-ethylhexyl)oxy)-2-methoxy>xylene

α,α′-dibromo-2-methoxy-5-(2-ethylhexyloxy)xylene

2-(2-ethylhexyloxy)-5-methoxybenzene-1,4-dibromobenzene

tetraethyl 2-((2-ethylhexyl)oxy)-5-methoxy-1,4-phenylenebis(methylene)bis(phosphonate)