{tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene

Base Information

Chemical Name:{tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene
CAS No.:889876-82-8
Molecular Formula:C₂₀H₃₆O₂Si₂
Molecular Weight:364.676
Hs Code.:

{<i>tert</i>-butyl-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene

Synonyms:{tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene

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Chemical Property of {tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene

Chemical Property:

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Technology Process of {tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene

There total 2 articles about {tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 889876-81-7
(S)-allyloxy-tert-butyl-methoxy-phenyl-silane

: 69739-34-0
t-butyldimethylsiyl triflate

: 889876-82-8
{tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 - 0 ℃; for 3.66667h;
DOI:10.1002/anie.200503734

Reference yield:

: 259264-67-0
(S)-allyloxy-tert-butyl-phenylsilanol

: 889876-82-8
{tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene

Guidance literature:: Multi-step reaction with 2 steps

1: KH / tetrahydrofuran / 0 - 20 °C

2: t-BuLi; HMPA / tetrahydrofuran; pentane / 3.67 h / -78 - 0 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; tert.-butyl lithium; potassium hydride; In tetrahydrofuran; pentane; 2: <1,4>-retro-Brook rearrangement;
DOI:10.1002/anie.200503734

Reference yield:

: 889876-82-8
{tert-butyl-[3-(tert-butyl-dimethyl-silanyloxy)-allyl]-methoxy-silanyl}-benzene

: 3-(tert-butyl-methoxy-phenyl-silanyl)-propan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: Acid hydrolysis

2: DIBAL / CH₂Cl₂; hexane / 0.75 h / -78 °C

With diisobutylaluminium hydride; In hexane; dichloromethane;
DOI:10.1002/anie.200503734