[1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)][Ni(maleonitriledithionate)2]

Base Information

• Chemical Name: [1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)][Ni(maleonitriledithionate)2]
• CAS No.: 1178962-52-1
• Molecular Formula: C₈N₄NiS₄*C₁₄H₁₅BrFN₂
• Molecular Weight: 649.258
• Mol file: 1178962-52-1.mol

Synonyms:[1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)][Ni(maleonitriledithionate)2]

Chemical Property of [1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)][Ni(maleonitriledithionate)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)][Ni(maleonitriledithionate)2]

There total 2 articles about [1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)][Ni(maleonitriledithionate)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

[1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)]2[Ni(maleonitriledithionate)2] → [1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)][Ni(maleonitriledithionate)2] (1178962-52-1)

Guidance literature:

With I₂; In methanol; acetone; soln. of I2 in acetone was added to soln. of nickel complex in acetone, stirred for 12 h; MeOH was added, allowed to stand overnight, crystals were filtered off, washed with MeOH, dried in vac., elem. anal.;

DOI:10.1016/j.ica.2009.04.021

Reference yield:

1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium bromide (1178962-53-2) → [1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium)][Ni(maleonitriledithionate)2] (1178962-52-1)

Guidance literature:

Multi-step reaction with 2 steps

1: water; methanol

2: I₂ / acetone; methanol

With I₂; In methanol; water; acetone;

DOI:10.1016/j.ica.2009.04.021

upstream raw materials:

1-(4'-fluoro-2'-bromobenzyl)-4-dimethylaminopyridinium bromide