Technology Process of C15H14BNO4S
There total 3 articles about C15H14BNO4S which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
N-tosyl-5-bromoindole;
With
potassium hydride;
In
tetrahydrofuran;
at 0 ℃;
for 0.25h;
With
tert.-butyl lithium;
In
tetrahydrofuran; pentane;
for 0.183333h;
With
Trimethyl borate;
In
tetrahydrofuran; pentane;
at -78 - 20 ℃;
DOI:10.1021/jo0491612
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran / -78 - 0 °C
1.2: 76 percent / tetrahydrofuran / 12 h / 20 °C
2.1: KH / tetrahydrofuran / 0.25 h / 0 °C
2.2: t-BuLi / tetrahydrofuran; pentane / 0.18 h
2.3: B(OMe)3 / tetrahydrofuran; pentane / -78 - 20 °C
With
n-butyllithium; potassium hydride;
In
tetrahydrofuran;
DOI:10.1021/jo0491612
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran / -78 - 0 °C
1.2: 76 percent / tetrahydrofuran / 12 h / 20 °C
2.1: KH / tetrahydrofuran / 0.25 h / 0 °C
2.2: t-BuLi / tetrahydrofuran; pentane / 0.18 h
2.3: B(OMe)3 / tetrahydrofuran; pentane / -78 - 20 °C
With
n-butyllithium; potassium hydride;
In
tetrahydrofuran;
DOI:10.1021/jo0491612