Technology Process of [Co(NC4H2)3(C(C6H5))4NC4N2C12H6N2]
There total 8 articles about [Co(NC4H2)3(C(C6H5))4NC4N2C12H6N2] which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
EDTA;
In
dichloromethane;
soln. of Co complex added to EDTA buffer soln., stirred at room temp. for 24 h; organic layer sepd., washed with sodium bicarbonate soln., dried, concd.; elem. anal.;
DOI:10.1016/j.ica.2010.07.008
- Guidance literature:
-
C56H34N8;
With
cobalt(II) chloride;
In
N,N-dimethyl-formamide;
for 12h;
Inert atmosphere;
Reflux;
With
sodium acetate; edetate disodium; acetic acid;
In
dichloromethane; water;
at 20 ℃;
for 24h;
pH=4.7;
DOI:10.1016/j.ica.2010.07.008
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: acetic anhydride; copper(II) nitrate / dichloromethane / 20 h / 20 °C / Inert atmosphere
2.1: sulfuric acid / dichloromethane / 0.13 h / 20 °C / Inert atmosphere
3.1: hydrogenchloride; tin(ll) chloride / dichloromethane; water / 0.5 h / 60 °C / Inert atmosphere; Microwave irradiation
3.2: 1 h / Inert atmosphere; UV-irradiation
4.1: trifluoroacetic acid / dichloromethane / 24 h / Inert atmosphere; Reflux
5.1: cobalt(II) chloride / N,N-dimethyl-formamide / 12 h / Inert atmosphere; Reflux
5.2: 24 h / 20 °C / pH 4.7
With
hydrogenchloride; sulfuric acid; acetic anhydride; copper(II) nitrate; trifluoroacetic acid; cobalt(II) chloride; tin(ll) chloride;
In
dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.ica.2010.07.008
![[Co(NC<sub>4</sub>H<sub>2</sub>)3(C(C<sub>6</sub>H<sub>5</sub>))4NC<sub>4</sub>N<sub>2</sub>C<sub>12</sub>H<sub>6</sub>N<sub>2</sub>(CoCl<sub>2</sub>)]](/Databaselist/images/loading.webp)
