(1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one

Base Information

Chemical Name:(1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one
CAS No.:150674-64-9
Molecular Formula:C₁₈H₂₅NO₅S
Molecular Weight:367.466
Hs Code.:

(1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopenta<c>pyrrol-5-one

Synonyms:(1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one

Chemical Property:

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Technology Process of (1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one

There total 11 articles about (1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (S)-3-Methoxymethoxymethyl-6-methyl-2-(toluene-4-sulfonyl)-2,3,3a,4-tetrahydro-1H-cyclopenta[c]pyrrol-5-one

: (1S,3aR,4R,6aR)-1-Methoxymethoxymethyl-4-methyl-2-(toluene-4-sulfonyl)-hexahydro-cyclopenta[c]pyrrol-5-one

: 150674-64-9
(1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; under 760 Torr;
DOI:10.1016/S0040-4039(00)79176-3

Reference yield:

: 1026379-71-4
(3S,3aS)-3-Hydroxymethyl-6-methyl-2,3,3a,4-tetrahydro-1H-cyclopenta[c]pyrrol-5-one

: 150674-64-9
(1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one

Guidance literature:: Multi-step reaction with 3 steps

1: Ambient temperature

2: 98 percent / H₂ / 10percent Pd/C / ethyl acetate / 1 h / 760 Torr

3: diisopropylethylamine / CH₂Cl₂ / 3 h / Ambient temperature

With hydrogen; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In dichloromethane; ethyl acetate;
DOI:10.1021/jo00102a021

Reference yield:

: 158839-32-8
(S)-3-(but-2-ynyl)-4-vinyloxazolidin-2-one

: 150674-64-9
(1S,3aS,4S,6aS)-1-(Methoxymethoxymethyl)-4-methyl-2-(toluene-4-sulfonyl)hexahydrocyclopentapyrrol-5-one

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Co₂(CO)8, 2.) Me₃NO / 1.) CH₂CL₂, r.t., 1 h, 2.) r.t., 2 h

2: 4 N aq. HCl / 6 h / Heating

3: Ambient temperature

4: 98 percent / H₂ / 10percent Pd/C / ethyl acetate / 1 h / 760 Torr

5: diisopropylethylamine / CH₂Cl₂ / 3 h / Ambient temperature

With hydrogenchloride; dicobalt octacarbonyl; trimethylamine-N-oxide; hydrogen; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In dichloromethane; ethyl acetate;
DOI:10.1021/jo00102a021