(E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate

Base Information

Chemical Name:(E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate
CAS No.:897398-14-0
Molecular Formula:C₃₀H₃₈O₆
Molecular Weight:494.628
Hs Code.:

Synonyms:(E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate

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Chemical Property of (E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate

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Technology Process of (E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate

There total 5 articles about (E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 897398-23-1
(E)-5-(hydroxymethyl)-3-[(3-methoxyphenyl)methylene]-5-[(phenylmethoxy)methyl]-4,5-dihydrofuran-2-one

: 261356-89-2
4-methyl-3-(1-methylethyl)pentanoyl chloride

: 897398-14-0
(E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃;
DOI:10.1021/jm060011o

Reference yield:

: 897397-94-3
3-[hydroxy-(3-methoxyphenyl)methyl]-5-[(4-methoxyphenoxy)methyl]-5-[(phenylmethoxy)methyl]-3,4,5-trihydrofuran-2-one

: 897398-14-0
(E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: Et₃N; MsCl / CH₂Cl₂ / 0.5 h / 20 °C

1.2: 38 percent / diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 20 °C

2.1: 66 percent / ceric ammonium nitrate / acetonitrile; H₂O / 0.5 h / 0 °C

3.1: 70 percent / Et₃N; DMAP / CH₂Cl₂ / 20 °C

With dmap; ammonium cerium(IV) nitrate; methanesulfonyl chloride; triethylamine; In dichloromethane; water; acetonitrile;
DOI:10.1021/jm060011o

Reference yield:

: 897398-04-8
(E)-3-[(3-methoxyphenyl)methylene]-5-[(4-methoxyphenoxy)methyl]-5-[(phenylmethoxy)methyl]-4,5-dihydrofuran-2-one

: 897398-14-0
(E)-{4-[(3-methoxyphenyl)methylene]-5-oxo-2-[(phenylmethoxy)methyl]-2,3-dihydrofur-2-yl}methyl 4-methyl-3-(methylethyl)pentanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 66 percent / ceric ammonium nitrate / acetonitrile; H₂O / 0.5 h / 0 °C

2: 70 percent / Et₃N; DMAP / CH₂Cl₂ / 20 °C

With dmap; ammonium cerium(IV) nitrate; triethylamine; In dichloromethane; water; acetonitrile;
DOI:10.1021/jm060011o