(5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate

Base Information

Chemical Name:(5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate
CAS No.:476158-23-3
Molecular Formula:C₂₇H₂₀N₂O₄
Molecular Weight:436.467
Hs Code.:

Synonyms:(5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate

Suppliers and Price of (5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of (5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate

There total 6 articles about (5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 95-54-5
1,2-diamino-benzene

: 737805-27-5
(5-exo,6-exo)-5,6-dibenzoyloxybicyclo[2.2.1]heptane-2,3-dione

: 476158-23-3
(5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate

Guidance literature:: With ZnCl₂[C₆H₅CH(NH₂)CH₃]2; In tetrahydrofuran; for 18h; Heating;
DOI:10.1016/j.tet.2004.08.038

Reference yield:

: (+/-)-(5-exo,6-exo)-5,6-dibenzoyloxybicyclo[2.2.1]heptan-2-one

: 476158-23-3
(5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 74 percent / SeO₂ / xylene / 24 h / Heating

2: 79 percent / ZnCl₂[C₆H₅CH(NH₂)CH₃]2 / tetrahydrofuran / 18 h / Heating

With selenium(IV) oxide; ZnCl₂[C₆H₅CH(NH₂)CH₃]2; In tetrahydrofuran; xylene;
DOI:10.1016/j.tet.2004.08.038

Reference yield:

: (+/-)-(5-exo,6-exo)-5,6-dibenzoyloxybicyclo[2.2.1]heptan-2-ol

: 476158-23-3
(5-exo,6-exo)-1,2,3,4-tetrahydro-1,4-methanophenazine-2,3-diyl dibenzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 78 percent / CrO₃; pyridine / CH₂Cl₂ / 6 h / 0 °C

2: 74 percent / SeO₂ / xylene / 24 h / Heating

3: 79 percent / ZnCl₂[C₆H₅CH(NH₂)CH₃]2 / tetrahydrofuran / 18 h / Heating

With pyridine; chromium(VI) oxide; selenium(IV) oxide; ZnCl₂[C₆H₅CH(NH₂)CH₃]2; In tetrahydrofuran; dichloromethane; xylene;
DOI:10.1016/j.tet.2004.08.038