2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran

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Chemical Name:2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran
CAS No.:357670-32-7
Molecular Formula:C₂₁H₂₆O₃
Molecular Weight:326.436
Hs Code.:

Synonyms:2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran

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Chemical Property of 2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran

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Technology Process of 2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran

There total 4 articles about 2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 5631-96-9
2-(2-chloroethoxy)-tetrahydro-2H-pyrane

: 357670-29-2
3-phenylbicyclo[2.2.1]hepta-2,5-diene-2-methanol

: 357670-32-7
2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran

Guidance literature:: With sodium hydroxide; tetrabutylammomium bromide; In water; at 66 ℃; for 63h;
DOI:10.1021/jo015610b

Reference yield:

: 57273-96-8
3-phenylbicyclo[2.2.1]hepta-2,5-diene-2-carboxylic acid ethyl ester

: 357670-32-7
2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / diisobutylaluminum hydride / tetrahydrofuran; hexane / 2 h / -78 °C

2: 60 percent / tetrabutylammonium bromide; sodium hydroxide / H₂O / 63 h / 66 °C

With sodium hydroxide; tetrabutylammomium bromide; diisobutylaluminium hydride; In tetrahydrofuran; hexane; water;
DOI:10.1021/jo015610b

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 357670-32-7
2-[2-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-ylmethoxy)ethoxy]tetrahydro-2H-pyran

Guidance literature:: Multi-step reaction with 3 steps

1: 49 percent / 84 h / 160 °C

2: 75 percent / diisobutylaluminum hydride / tetrahydrofuran; hexane / 2 h / -78 °C

3: 60 percent / tetrabutylammonium bromide; sodium hydroxide / H₂O / 63 h / 66 °C

With sodium hydroxide; tetrabutylammomium bromide; diisobutylaluminium hydride; In tetrahydrofuran; hexane; water; 1: Diels-Alder reaction;
DOI:10.1021/jo015610b