Tricyclo[2.2.1.02,6]heptane-3-carboxylic acid, methyl ester, stereoisomer (9CI)

Base Information

Chemical Name:Tricyclo[2.2.1.02,6]heptane-3-carboxylic acid, methyl ester, stereoisomer (9CI)
CAS No.:132672-03-8
Molecular Formula:C9H12O2
Molecular Weight:152.19038
Hs Code.:
Mol file:132672-03-8.mol

Synonyms:Tricyclo[2.2.1.02,6]heptane-3-carboxylic acid, methyl ester, stereoisomer (9CI)

Suppliers and Price of Tricyclo[2.2.1.02,6]heptane-3-carboxylic acid, methyl ester, stereoisomer (9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Tricyclo[2.2.1.02,6]heptane-3-carboxylic acid, methyl ester, stereoisomer (9CI)

Chemical Property:

Purity/Quality:

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Technology Process of Tricyclo[2.2.1.02,6]heptane-3-carboxylic acid, methyl ester, stereoisomer (9CI)

There total 11 articles about Tricyclo[2.2.1.02,6]heptane-3-carboxylic acid, methyl ester, stereoisomer (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 16745-79-2,56918-44-6,132672-03-8
methyl (R)-(+)-tricyclo<2.2.1.0^2,6>heptane-3-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: dimethylformamide / 95 h / 115 - 120 °C

2: 93 percent / NaIO₄ / methanol; H₂O / 0.5 h / Ambient temperature

3: Cl / toluene / 43 h / Heating

With sodium periodate; bis[1,3-bis(diphenylphosphino)propane]rhodium chloride; In methanol; water; N,N-dimethyl-formamide; toluene;
DOI:10.1016/0008-6215(92)84148-L

Reference yield:

: 136520-61-1
methyl (5R,6R)-6-endo-(L-arabino-tetritol-1-yl)bicyclo<2.2.1>hept-2-eno-5-exo-carboxylate

: 16745-79-2,56918-44-6,132672-03-8
methyl (R)-(+)-tricyclo<2.2.1.0^2,6>heptane-3-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / NaIO₄ / methanol; H₂O / 0.5 h / Ambient temperature

2: Cl / toluene / 43 h / Heating

With sodium periodate; bis[1,3-bis(diphenylphosphino)propane]rhodium chloride; In methanol; water; toluene;
DOI:10.1016/0008-6215(92)84148-L

Reference yield:

: 136520-58-6
methyl (5R,6R)-6-endo-formylbicyclo<2.2.1>hept-2-eno-5-exo-carboxylate

: 769-85-7,2903-75-5,6203-08-3,72203-34-0,78037-76-0,84235-37-0,92936-02-2,92936-03-3,68069-49-8
bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

: 769-85-7,2903-75-5,6203-08-3,68069-49-8,72203-34-0,78037-76-0,84235-37-0,92936-02-2,92936-03-3
exo-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

: 16745-79-2,56918-44-6,132672-03-8
methyl (R)-(+)-tricyclo<2.2.1.0^2,6>heptane-3-carboxylate

Guidance literature:: With bis[1,3-bis(diphenylphosphino)propane]rhodium chloride; In toluene; for 43h; Yield given. Yields of byproduct given; Heating;
DOI:10.1016/0008-6215(92)84148-L