1-Cyclopentene-1-carboxylicacid,3-hydroxy-2-methyl-,methylester,(3S)-

Base Information

Chemical Name:1-Cyclopentene-1-carboxylicacid,3-hydroxy-2-methyl-,methylester,(3S)-
CAS No.:459174-10-8
Molecular Formula:C8H12O3
Molecular Weight:0
Hs Code.:
Mol file:459174-10-8.mol

Synonyms:1-Cyclopentene-1-carboxylicacid,3-hydroxy-2-methyl-,methylester,(3S)-

Suppliers and Price of 1-Cyclopentene-1-carboxylicacid,3-hydroxy-2-methyl-,methylester,(3S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 1-Cyclopentene-1-carboxylicacid,3-hydroxy-2-methyl-,methylester,(3S)-

Chemical Property:

PSA：46.53000
LogP:0.63060

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1-Cyclopentene-1-carboxylicacid,3-hydroxy-2-methyl-,methylester,(3S)-

There total 2 articles about 1-Cyclopentene-1-carboxylicacid,3-hydroxy-2-methyl-,methylester,(3S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 5453-05-4
methyl 2-methyl-3-oxocyclopent-1-ene-1-carboxylate

: 459174-10-8
(S)-(-)-methyl 3-hydroxy-2-methylcyclopent-1-enecarboxylate

Guidance literature:: With dimethylsulfide borane complex; (R)-1-CH₃-3,3-(C₆H₅)2-C₅H₇BNO; In toluene; at -20 - -15 ℃; for 2h;
DOI:10.1021/jo025883m

Reference yield:

: 146860-08-4
(+/-)-methyl 3-hydroxy-2-methylcyclopent-1-enecarboxylate

: 5453-05-4
methyl 2-methyl-3-oxocyclopent-1-ene-1-carboxylate

: 459174-10-8
(S)-(-)-methyl 3-hydroxy-2-methylcyclopent-1-enecarboxylate

Guidance literature:: With oxygen; caesium carbonate; (-)-sparteine; In chloroform; at 23 ℃; for 10h; under 760.051 Torr; optical yield given as %ee; Molecular sieve;
DOI:10.1002/chem.200902172

Reference yield:

: 459174-10-8
(S)-(-)-methyl 3-hydroxy-2-methylcyclopent-1-enecarboxylate

: 459174-16-4
(2S,3S)-3-Hydroxy-2-methyl-cyclopentanecarboxylic acid methyl ester

Guidance literature:: With sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; toluene; at -40 - -25 ℃; for 2.5h;
DOI:10.1021/jo025883m