N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine

Base Information

Chemical Name:N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine
CAS No.:138384-52-8
Molecular Formula:C₂₅H₂₁N₃O₂S
Molecular Weight:427.527
Hs Code.:

N<sup>6</sup>-methyl-N<sup>6</sup>-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenz<cd>indole-2,6-diamine

Synonyms:N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine

Chemical Property:

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Technology Process of N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine

There total 12 articles about N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 138385-05-4
N⁶-<4-(phenylsulfonyl)benzyl>-N⁶-methyl-2-(methylthio)-6-aminobenzindole

: 138384-52-8
N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine

Guidance literature:: With ammonia; In methanol; at 145 ℃; for 5h;
DOI:10.1021/jm00082a006

Reference yield:

: 130-00-7
1,8-naphtholactam

: 138384-52-8
N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine

Guidance literature:: Multi-step reaction with 7 steps

1: 51 percent / 70percent HNO₃ / acetic acid / 1 h / 20 - 50 °C

2: H₂ / 5percent Pd/C / tetrahydrofuran / 16 h / 2068.6 Torr

3: 71 percent / DIEA / dimethylformamide / 3 h / 75 °C

4: 26 percent / DIEA / dimethylformamide / 19 h / 95 °C

5: 47 percent / Lawesson's reagent / toluene / 1 h / 120 °C

6: 95 percent / 1 N NaOH / aq. ethanol; tetrahydrofuran / 0.5 h / 25 °C

7: 87 percent / NH₃ / methanol / 5 h / 145 °C

With Lawessons reagent; sodium hydroxide; ammonia; hydrogen; nitric acid; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; ethanol; acetic acid; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jm00082a006

Reference yield:

: 65300-66-5
N-(2,4-dinitrophenoxy)-4-nitronaphthalimide

: 138384-52-8
N⁶-methyl-N⁶-<<4-(phenylsulfonyl)phenyl>methyl>-6-aminobenzindole-2,6-diamine

Guidance literature:: Multi-step reaction with 7 steps

1: NaOH / ethanol; H₂O / 16 h / 25 °C

2: H₂ / 5percent Pd/C / tetrahydrofuran / 16 h / 2068.6 Torr

3: 71 percent / DIEA / dimethylformamide / 3 h / 75 °C

4: 26 percent / DIEA / dimethylformamide / 19 h / 95 °C

5: 47 percent / Lawesson's reagent / toluene / 1 h / 120 °C

6: 95 percent / 1 N NaOH / aq. ethanol; tetrahydrofuran / 0.5 h / 25 °C

7: 87 percent / NH₃ / methanol / 5 h / 145 °C

With Lawessons reagent; sodium hydroxide; ammonia; hydrogen; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; ethanol; water; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jm00082a006