(E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol

Base Information

Chemical Name:(E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol
CAS No.:1431665-47-2
Molecular Formula:C₂₅H₂₈OSeSi
Molecular Weight:451.542
Hs Code.:

Synonyms:(E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol

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Chemical Property of (E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol

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Technology Process of (E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol

There total 5 articles about (E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₁H₄₀O₃SeSiTi

: 1431665-47-2
(E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol

Guidance literature:: With water; at -70 ℃; regioselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2013.03.060

Reference yield:

: 768-33-2
phenyldimethylsilyl chloride

: 1431665-47-2
(E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.33 h / -78 °C / Inert atmosphere

1.2: 0.17 h / 0 °C / Inert atmosphere

2.1: isopropylmagnesium chloride / diethyl ether / 2.5 h / -78 - -50 °C / Inert atmosphere

3.1: 1 h / -70 °C / Inert atmosphere

4.1: water / -70 °C / Inert atmosphere

With n-butyllithium; water; isopropylmagnesium chloride; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1016/j.tet.2013.03.060

Reference yield:

: 1431665-36-9
dimethyl(phenyl)[4-(phenylselanyl)but-1-yn-1-yl]silane

: 1431665-47-2
(E)-2-[(dimethylphenylsilyl)methylene]-1-phenyl-4-(phenylselanyl)butan-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: isopropylmagnesium chloride / diethyl ether / 2.5 h / -78 - -50 °C / Inert atmosphere

2: 1 h / -70 °C / Inert atmosphere

3: water / -70 °C / Inert atmosphere

With water; isopropylmagnesium chloride; In diethyl ether;
DOI:10.1016/j.tet.2013.03.060