[(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate

Base Information

• Chemical Name: [(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate
• CAS No.: 465500-50-9
• Molecular Formula: C₂₃H₂₀AuF₅NO₂P
• Molecular Weight: 665.35
• Mol file: 465500-50-9.mol

Synonyms:[(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate

Chemical Property of [(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate

There total 1 articles about [(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.5%

p-N,N-dimethylaminophenyldiphenylphosphanegold(I) chloride (137008-26-5) + silver(I) pentafluoropropionate (509-09-1) → [(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate (465500-50-9)

Guidance literature:

In dichloromethane; byproducts: AgCl; under dry N2, 1 equiv. of Ag-salt was added in CH2Cl2 suspn. to CH2Cl2-soln. of Au-complex at -78 °C with stirring under light exclusion,stirring for 12 h; mixt. was filtered, pptn. with adding of pentane, ppt. was filtered off,recrystd. from CH2Cl2, elem. anal.;

DOI:10.1515/znb-2002-0602

Reference yield: 84.0%

[(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate (465500-50-9) + silver(I) pentafluoropropionate (509-09-1) → bis[(4-dimethylaminophenyl)diphenylphosphine]digold(I)-disilver(I) tetrakis(pentafluoropropionate)

Guidance literature:

In dichloromethane; under N2; C2F5CO2Ag suspended in CH2Cl2, cooled to -70°C; treatedwith soln. of ((4-Me2N-C6H4)Ph2)PAuOC(O)C2F5 in CH2Cl2; stirred for 2 h; soln. concd. under vac.; cold pentane (-70°C) added; ppt. recrystd. from CH2Cl2/pentane; elem. anal.;

DOI:10.1016/S0020-1693(03)00468-7

Reference yield:

[(4-dimethylaminophenyl)diphenylphosphine]gold(I) pentafluoropropionate (465500-50-9) → gold (7440-57-5,457905-15-6)

Guidance literature:

In neat (no solvent); heating on solid substrates, under dry N2;

DOI:10.1515/znb-2002-0602

upstream raw materials:

p-N,N-dimethylaminophenyldiphenylphosphanegold(I) chloride

silver(I) pentafluoropropionate

Downstream raw materials:

gold

Refernces

• 1、 R?mbke, Patric,Schier, Annette,Schmidbaur, Hubert. "Gold(I) carboxylates and fluorocarboxylates". . p. 605 - 609. Retrieved 2007/10/03.