Technology Process of (8,18-13C2)-(E)-2-(2,2,6-trimethylcyclohexen-1-yl)ethenyl nonafluorobutanesulfonate
There total 5 articles about (8,18-13C2)-(E)-2-(2,2,6-trimethylcyclohexen-1-yl)ethenyl nonafluorobutanesulfonate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: LDA / tetrahydrofuran; hexane / 0.5 h / -70 °C
1.2: 79 percent / tetrahydrofuran; hexane / 2 h / -70 °C
2.1: 93 percent / thionyl chloride; pyridine / 0.17 h / 9 °C
3.1: LiAlH4 / diethyl ether / 0.5 h / 0 °C
4.1: diisopropylmagnesium bromide / tetrahydrofuran / 0.17 h / 0 °C
4.2: 870 mg / azodicarbonyldipiperidine / tetrahydrofuran / 2 h / 0 °C
5.1: 63 percent / t-BuOK / tetrahydrofuran / 1 h / Heating
With
pyridine; lithium aluminium tetrahydride; thionyl chloride; diisopropylmagnesium bromide; potassium tert-butylate; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; hexane;
DOI:10.1055/s-2005-865294
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: diisopropylmagnesium bromide / tetrahydrofuran / 0.17 h / 0 °C
1.2: 870 mg / azodicarbonyldipiperidine / tetrahydrofuran / 2 h / 0 °C
2.1: 63 percent / t-BuOK / tetrahydrofuran / 1 h / Heating
With
diisopropylmagnesium bromide; potassium tert-butylate;
In
tetrahydrofuran;
DOI:10.1055/s-2005-865294
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 93 percent / thionyl chloride; pyridine / 0.17 h / 9 °C
2.1: LiAlH4 / diethyl ether / 0.5 h / 0 °C
3.1: diisopropylmagnesium bromide / tetrahydrofuran / 0.17 h / 0 °C
3.2: 870 mg / azodicarbonyldipiperidine / tetrahydrofuran / 2 h / 0 °C
4.1: 63 percent / t-BuOK / tetrahydrofuran / 1 h / Heating
With
pyridine; lithium aluminium tetrahydride; thionyl chloride; diisopropylmagnesium bromide; potassium tert-butylate;
In
tetrahydrofuran; diethyl ether;
DOI:10.1055/s-2005-865294
