Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate

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Chemical Name:Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate
CAS No.:113396-99-9
Molecular Formula:C₁₄H₁₃N₂O₄S*K
Molecular Weight:344.433
Hs Code.:

Synonyms:Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate

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Chemical Property of Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate

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Technology Process of Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate

There total 6 articles about Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 113396-95-5
(2R,5S,6R)-6-((S)-1-Hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 4-nitro-benzyl ester

: 113396-99-9
Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate

: 113396-98-8
Potassium; (5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-phenylamino-4-thia-1-aza-bicyclo[3.2.0]hept-2-ene-2-carboxylate

Guidance literature:: With hydrogen; potassium hydrogencarbonate; palladium on activated charcoal; In water; ethyl acetate; under 3040 Torr;
DOI:10.1016/S0040-4039(00)96102-1

Reference yield:

: 85768-12-3
{(2S,3R)-3-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-ethylsulfanyl-4-oxo-azetidin-1-yl}-acetic acid 4-nitro-benzyl ester

: 113396-99-9
Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate

Guidance literature:: Multi-step reaction with 5 steps

1: lithium hexamethyldisilazide

2: 5M aq. HCl / tetrahydrofuran / 20 °C

3: Cl₂ / CCl₄; CHCl₃ / 0 °C

4: 15 percent / imidazole / H₂O; dioxane

5: hydrogen, KHCO₃ / 10percent Pd-C / ethyl acetate; H₂O / 3040 Torr

With 1H-imidazole; hydrogenchloride; hydrogen; chlorine; potassium hydrogencarbonate; lithium hexamethyldisilazane; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; tetrachloromethane; chloroform; water; ethyl acetate;
DOI:10.1016/S0040-4039(00)96102-1

Reference yield:

: 113396-93-3
(Z)-3-Acetylsulfanyl-2-[(2R,3R)-2-chloro-3-((S)-1-hydroxy-ethyl)-4-oxo-azetidin-1-yl]-3-phenylamino-acrylic acid 4-nitro-benzyl ester

: 113396-99-9
Potassium; (2S,5R,6S)-6-((R)-1-hydroxy-ethyl)-7-oxo-3-[(Z)-phenylimino]-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 15 percent / imidazole / H₂O; dioxane

2: hydrogen, KHCO₃ / 10percent Pd-C / ethyl acetate; H₂O / 3040 Torr

With 1H-imidazole; hydrogen; potassium hydrogencarbonate; palladium on activated charcoal; In 1,4-dioxane; water; ethyl acetate;
DOI:10.1016/S0040-4039(00)96102-1