bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)

Base Information

Chemical Name:bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)
CAS No.:90739-53-0
Molecular Formula:C₂₀H₁₀Mn₂O₈P*C₃₆H₃₀NP₂
Molecular Weight:1057.73
Hs Code.:

Synonyms:bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)

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Chemical Property of bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)

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Technology Process of bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)

There total 1 articles about bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 16940-66-2
sodium tetrahydroborate

: [Mn2(μ-H)(μ-PPh2)(CO)8]

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 90739-53-0
bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)

Guidance literature:: In acetonitrile; Mn-complex and NaBH4 were refluxed in MeCN for 30 min under N2, ligand was added, followed by H2O, ppt. was extd. with CH2Cl2, organic layer dried with Na2SO4; soln. was taken to dryness, washed with hexane, recrystd. from CH2Cl2-hexane; elem. anal.;

Reference yield: 95.0%

: 90739-53-0
bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)

: 4Cu*4I*4P(C₂H₅)3=(CuI(P(C₂H₅)3))4

: Mn₂CuP(C₂H₅)3(P(C₆H₅)2)(CO)8

Guidance literature:: With AgClO₄; In dichloromethane; Cu-complex was stirred in CH2Cl2 soln. over AgClO4 for ca. 15 min, soln. was filtered under N2 onto Mn-complex in CH2Cl2 for 15 min; mixt. was taken to dryness, residue redissolved in CH2Cl2, sepd. by chromy. with hexane-CH2Cl2 as eluant; elem. anal.;

Reference yield: 90.0%

: 90739-53-0
bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)

: 4Ag*4I*4P(C₂H₅)3=(AgI(P(C₂H₅)3))4

: Mn₂AgP(C₂H₅)3(P(C₆H₅)2)(CO)8

Guidance literature:: With AgClO₄; In dichloromethane; Ag-complex was stirred in CH2Cl2 soln. over AgClO4 for ca. 15 min, soln. was filtered under N2 onto Mn-complex in CH2Cl2 for 15 min; mixt. was taken to dryness, residue redissolved in CH2Cl2, sepd. by chromy. with hexane-CH2Cl2 as eluant; elem. anal.;