2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol

Base Information

Chemical Name:2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol
CAS No.:636560-77-5
Molecular Formula:C₂₆H₃₀N₁₂O₅
Molecular Weight:590.602
Hs Code.:

Synonyms:2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol

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Chemical Property of 2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol

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Technology Process of 2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol

There total 6 articles about 2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 69048-60-8
meso-(1R,3S,4S,6R)-4,6-diazidocyclohexane-1,3-diol

: (2R,3R,4S,5R,6S)-3-Azido-2-azidomethyl-4,5-bis-benzyloxy-6-ethylsulfanyl-tetrahydro-pyran

: 636560-77-5
2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol

Guidance literature:: With N-iodo-succinimide; 4 A molecular sieve; silver trifluoromethanesulfonate; In diethyl ether; dichloromethane; toluene; at -40 ℃; for 5h;
DOI:10.1055/s-2003-40351

Reference yield:

: 20701-61-5,56119-28-9,131564-36-8,142924-31-0,151123-92-1,141899-53-8
ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside

: 636560-77-5
2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol

Guidance literature:: Multi-step reaction with 5 steps

1: TBAI; NaH

2: AcOH

3: 67 percent / NaN₃

4: 34 percent / 4 Angstroem molecular sieves; NIS; AgOTf / CH₂Cl₂; diethyl ether; toluene / 5 h / -40 °C

With N-iodo-succinimide; sodium azide; 4 A molecular sieve; silver trifluoromethanesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; acetic acid; In diethyl ether; dichloromethane; toluene;
DOI:10.1055/s-2003-40351

Reference yield:

: 152964-70-0
ethyl 2,3-di-O-benzyl-1-thio-β-D-glucopyranoside

: 636560-77-5
2,4-Diazido-5-((2S,3R,4S,5R,6R)-5-azido-6-azidomethyl-3,4-bis-benzyloxy-tetrahydro-pyran-2-yloxy)-cyclohexanol

Guidance literature:: Multi-step reaction with 3 steps

1: 67 percent / NaN₃

2: 34 percent / 4 Angstroem molecular sieves; NIS; AgOTf / CH₂Cl₂; diethyl ether; toluene / 5 h / -40 °C

With N-iodo-succinimide; sodium azide; 4 A molecular sieve; silver trifluoromethanesulfonate; In diethyl ether; dichloromethane; toluene;
DOI:10.1055/s-2003-40351