benzylaminepentacarbonylmolybdenum

Base Information

• Chemical Name: benzylaminepentacarbonylmolybdenum
• CAS No.: 29139-30-8
• Molecular Formula: C₅MoO₅*C₇H₉N
• Molecular Weight: 343.147
• Mol file: 29139-30-8.mol

Synonyms:benzylaminepentacarbonylmolybdenum

Chemical Property of benzylaminepentacarbonylmolybdenum

Chemical Property:

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Technology Process of benzylaminepentacarbonylmolybdenum

There total 1 articles about benzylaminepentacarbonylmolybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzylamine (100-46-9) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → (benzylamine)molybdenum pentacarbonyl (29139-30-8)

Guidance literature:

In decalin; byproducts: CO; N2-atmosphere; excess of amine, 102.00-112.00°C; not isolated, reaction followed by IR spectroscopy; Kinetics;

DOI:10.1016/S0020-1693(00)94117-3

Reference yield: 97.0%

iodobenzene (591-50-4) + benzylaminepentacarbonylmolybdenum (29139-30-8) → N-benzylbenzamide (1485-70-7)

Guidance literature:

With tributyl-amine; In diethylene glycol dimethyl ether; at 150 ℃; for 1h; Inert atmosphere;

DOI:10.1021/jo1002592

Reference yield: 95.0%

iodobenzene (591-50-4) + benzylaminepentacarbonylmolybdenum (29139-30-8) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → (1,2-bis(diphenylphosphino)ethane)tetracarbonylmolybdenum (15444-66-3) + N-benzylbenzamide (1485-70-7)

Guidance literature:

iodobenzene; benzylaminepentacarbonylmolybdenum; With tributyl-amine; In diethylene glycol dimethyl ether; at 150 ℃; for 1h; Inert atmosphere;

1,2-bis-(diphenylphosphino)ethane; In diethylene glycol dimethyl ether; at 20 - 150 ℃; Inert atmosphere;

DOI:10.1021/jo1002592

upstream raw materials:

benzylamine

molybdenum hexacarbonyl

Downstream raw materials:

dibromo(benzylamine)molybdenum tetracarbonyl

diiodo(benzylamine)molybdenum tetracarbonyl

N-benzylbenzamide

N-benzylthiophene-3-carboxamide