2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester

Base Information

Chemical Name:2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester
CAS No.:798573-59-8
Molecular Formula:C₁₈H₂₄ClNO₂
Molecular Weight:321.847
Hs Code.:

Synonyms:2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester

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Chemical Property of 2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester

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Technology Process of 2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester

There total 5 articles about 2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 491861-10-0
methyl 2-((2E,6E)-8-hydroxy-2,6-dimethyl-octa-2,6-dienylamino)benzoate

: 798573-59-8
2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester

Guidance literature:: With N-chloro-succinimide; dimethylsulfide; In dichloromethane; at 0 ℃; for 3h;
DOI:10.1021/jo049101w

Reference yield:

: 37905-02-5
(2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate

: 798573-59-8
2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: K₂CO₃ / methanol / 2.5 h / 20 °C

2.1: 3.89 g / i-Pr₂NEt / tetrahydrofuran / 2 h / 0 °C

3.1: acetic acid / 1,2-dichloro-ethane / 0.08 h / 20 °C

3.2: 89 percent / NaBH(OAc)3 / 1,2-dichloro-ethane / 2.7 h / 20 °C

4.1: 90 percent / tetrabutylammonium fluoride / tetrahydrofuran / 2 h / 0 °C

5.1: N-chlorosuccinimide; dimethyl sulfide / CH₂Cl₂ / 3 h / 0 °C

With N-chloro-succinimide; dimethylsulfide; tetrabutyl ammonium fluoride; potassium carbonate; acetic acid; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/jo049101w

Reference yield:

: 38290-51-6
(2E,6E)-8-hydroxy-2,6-dimethylocta-2,6-dienal

: 798573-59-8
2-((2E,6E)-8-Chloro-2,6-dimethyl-octa-2,6-dienylamino)-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: 3.89 g / i-Pr₂NEt / tetrahydrofuran / 2 h / 0 °C

2.1: acetic acid / 1,2-dichloro-ethane / 0.08 h / 20 °C

2.2: 89 percent / NaBH(OAc)3 / 1,2-dichloro-ethane / 2.7 h / 20 °C

3.1: 90 percent / tetrabutylammonium fluoride / tetrahydrofuran / 2 h / 0 °C

4.1: N-chlorosuccinimide; dimethyl sulfide / CH₂Cl₂ / 3 h / 0 °C

With N-chloro-succinimide; dimethylsulfide; tetrabutyl ammonium fluoride; acetic acid; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/jo049101w