{(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime

Base Information

Chemical Name:{(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime
CAS No.:180040-80-6
Molecular Formula:C₃₂H₅₅NO₇Si
Molecular Weight:593.877
Hs Code.:

{(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime

Synonyms:{(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime

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Chemical Property of {(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime

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Technology Process of {(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime

There total 3 articles about {(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 171524-14-4
(3S,5S,8R,9R,11R)-1-(Benzyloxy)-3,5:9,11-di-O-isopropylidene-8-<oxy>-13-oxotridecane-3,5,9,11-tetrol

: 180040-80-6
{(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime

Guidance literature:: With hydroxylamine hydrochloride; sodium carbonate; In diethyl ether; water;
DOI:10.1021/jo9609337

Reference yield:

: 171524-13-3
(3S,5S,8R,9R,11R)-1-(Benzyloxy)-3,5:9,11-di-O-isopropylidene-8-<oxy>-13-tetradecene-3,5,9,11-tetrol

: 180040-80-6
{(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime

Guidance literature:: Multi-step reaction with 3 steps

1: OsO₄; NMO / 2-methyl-propan-2-ol; H₂O

2: NaIO₄ / ethanol; H₂O

3: NH₂OH*HCl; Na₂CO₃ / diethyl ether; H₂O

With sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; hydroxylamine hydrochloride; sodium carbonate; In diethyl ether; ethanol; water; tert-butyl alcohol; 1: hydroxylation / 2: Oxidation / 3: oximation;
DOI:10.1021/jo9609337

Reference yield:

: 3-{(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-propane-1,2-diol

: 180040-80-6
{(4R,6R)-6-[(R)-3-[(4R,6S)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-(tert-butyl-dimethyl-silanyloxy)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde oxime

Guidance literature:: Multi-step reaction with 2 steps

1: NaIO₄ / ethanol; H₂O

2: NH₂OH*HCl; Na₂CO₃ / diethyl ether; H₂O

With sodium periodate; hydroxylamine hydrochloride; sodium carbonate; In diethyl ether; ethanol; water; 1: Oxidation / 2: oximation;
DOI:10.1021/jo9609337