Technology Process of Tricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaene
There total 14 articles about Tricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium hydroxide; hydrazine hydrate;
In
diethylene glycol;
at 190 ℃;
for 3h;
- Guidance literature:
-
With
sodium;
In
tetrahydrofuran; ammonia;
Heating;
DOI:10.1021/ja00311a047
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 1.) chromium hexacarbonyl; 2.) 2,2,6,6-tetramethylpiperidine, n-butyllithium, HMPA; 3.) iodine / 1.) p-dioxane, reflux, 60 h; 2.) THF/hexane, -78 deg C, 1 h, then 0 deg C, 1 h; 3.) THF/hexane, 25 deg C, 8 h
2: 91 percent / sodium / tetrahydrofuran; liquid ammonia / Heating
With
2,2,6,6-tetramethyl-piperidine; N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; iodine; sodium; chromium(0) hexacarbonyl;
In
tetrahydrofuran; ammonia;
DOI:10.1021/ja00311a047
