C₅₃H₆₉ClO₁₀Si

Base Information

Chemical Name:C₅₃H₆₉ClO₁₀Si
CAS No.:910043-21-9
Molecular Formula:C₅₃H₆₉ClO₁₀Si
Molecular Weight:929.663
Hs Code.:

C<sub>53</sub>H<sub>69</sub>ClO<sub>10</sub>Si

Synonyms:C₅₃H₆₉ClO₁₀Si

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Chemical Property of C₅₃H₆₉ClO₁₀Si

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Technology Process of C₅₃H₆₉ClO₁₀Si

There total 19 articles about C₅₃H₆₉ClO₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 910043-20-8
C₆₁H₇₈O₁₂Si

: 910043-21-9
C₅₃H₆₉ClO₁₀Si

Guidance literature:: C₆₁H₇₈O₁₂Si; With water; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; for 1h;

With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine; In dichloromethane; at -40 - -25 ℃; for 0.25h;
DOI:10.1021/ja0581346

Reference yield:

: 910042-98-7
tert-butyl (2E,4E)-octa-2,4,6-trienoate

: 910043-21-9
C₅₃H₆₉ClO₁₀Si

Guidance literature:: Multi-step reaction with 19 steps

1.1: 70 g / K₂CO₃; CH₃SO₂NH₂; quinuclidine / K₂Os₂O₂(OH)4; K₃Fe(CN)6 / 2-methyl-propan-2-ol; H₂O / 6 h / 20 °C

2.1: 43.8 g / NaIO₄ / tetrahydrofuran; H₂O / 2 h / 0 - 20 °C

3.1: 26.8 g / NaBH₄; MeOH / tetrahydrofuran / 3 h / cooling

4.1: AgOTf; Na₂CO₃; 2,6-lutidine / CH₂Cl₂ / 0.33 h / cooling

4.2: CH₂Cl₂ / 16.5 h / -78 - 20 °C

4.3: 10.0 g / toluene / 14 h / 20 °C

5.1: 53 percent / NaHCO₃ / xylene / 114 h / Heating

6.1: 7.7 g / mCPBA; NaH₂PO₄*H₂O / CH₂Cl₂ / 21 h / 0 - 20 °C

7.1: 84 percent / DBU / tetrahydrofuran / 20 h / 20 °C

8.1: 100 percent / TFA / 0.5 h / 20 °C

9.1: ethyl chloroformate; triethylamine / CH₂Cl₂ / 0.5 h / cooling

9.2: 100 percent / NaBH₄; MeOH / tetrahydrofuran / 1.17 h / -40 - 0 °C

10.1: 4.0 g / DMAP; triethylamine / CH₂Cl₂ / 17 h / 0 - 20 °C

11.1: 84 percent / iPr₂NEt; DMAP / CH₂Cl₂ / 26 h / 20 - 40 °C

12.1: 92 percent / Zn-Ag couple; NaHCO₃ / methanol / 18 h / Heating

13.1: 69 percent / xylene / 5 h / Heating; ambient pressure

14.1: 86 percent / pyridinium p-toluenesulfonate / methanol / 14 h / Heating

15.1: 0.14 g / HMPA; NaN(TMS)2 / tetrahydrofuran; toluene / 18 h / -78 - 20 °C

16.1: 0.060 g / MeOH / benzene; petroleum ether / 0.5 h / 0 - 20 °C

17.1: 92 percent / DMP / CH₂Cl₂ / 1.17 h / 0 - 20 °C

18.1: DDQ; water / CH₂Cl₂ / 1 h / 20 °C

18.2: 75 percent / hexachloroacetone; PPh₃ / CH₂Cl₂ / 0.25 h / -40 - -25 °C

With Quinuclidine; 2,6-dimethylpyridine; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; sodium tetrahydroborate; sodium periodate; sodium dihydrogenphosphate; methanesulfonamide; phthalic acid dimethyl ester; water; silver trifluoromethanesulfonate; silver; sodium hexamethyldisilazane; pyridinium p-toluenesulfonate; chloroformic acid ethyl ester; sodium hydrogencarbonate; sodium carbonate; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; potassium osmate; potassium hexacyanoferrate(III); In tetrahydrofuran; methanol; dichloromethane; water; toluene; xylene; Petroleum ether; tert-butyl alcohol; benzene; 5.1: intramolecular Diels-Alder reactiom / 15.1: Dieckmann condensation;
DOI:10.1021/ja0581346

Reference yield:

: 910043-00-4
tert-butyl (E,E)-6-formylpenta-2,4-dienoate

: 910043-21-9
C₅₃H₆₉ClO₁₀Si

Guidance literature:: Multi-step reaction with 17 steps

1.1: 26.8 g / NaBH₄; MeOH / tetrahydrofuran / 3 h / cooling

2.1: AgOTf; Na₂CO₃; 2,6-lutidine / CH₂Cl₂ / 0.33 h / cooling

2.2: CH₂Cl₂ / 16.5 h / -78 - 20 °C

2.3: 10.0 g / toluene / 14 h / 20 °C

3.1: 53 percent / NaHCO₃ / xylene / 114 h / Heating

4.1: 7.7 g / mCPBA; NaH₂PO₄*H₂O / CH₂Cl₂ / 21 h / 0 - 20 °C

5.1: 84 percent / DBU / tetrahydrofuran / 20 h / 20 °C

6.1: 100 percent / TFA / 0.5 h / 20 °C

7.1: ethyl chloroformate; triethylamine / CH₂Cl₂ / 0.5 h / cooling

7.2: 100 percent / NaBH₄; MeOH / tetrahydrofuran / 1.17 h / -40 - 0 °C

8.1: 4.0 g / DMAP; triethylamine / CH₂Cl₂ / 17 h / 0 - 20 °C

9.1: 84 percent / iPr₂NEt; DMAP / CH₂Cl₂ / 26 h / 20 - 40 °C

10.1: 92 percent / Zn-Ag couple; NaHCO₃ / methanol / 18 h / Heating

11.1: 69 percent / xylene / 5 h / Heating; ambient pressure

12.1: 86 percent / pyridinium p-toluenesulfonate / methanol / 14 h / Heating

13.1: 0.14 g / HMPA; NaN(TMS)2 / tetrahydrofuran; toluene / 18 h / -78 - 20 °C

14.1: 0.060 g / MeOH / benzene; petroleum ether / 0.5 h / 0 - 20 °C

15.1: 92 percent / DMP / CH₂Cl₂ / 1.17 h / 0 - 20 °C

16.1: DDQ; water / CH₂Cl₂ / 1 h / 20 °C

16.2: 75 percent / hexachloroacetone; PPh₃ / CH₂Cl₂ / 0.25 h / -40 - -25 °C

With 2,6-dimethylpyridine; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; sodium tetrahydroborate; sodium dihydrogenphosphate; phthalic acid dimethyl ester; water; silver trifluoromethanesulfonate; silver; sodium hexamethyldisilazane; pyridinium p-toluenesulfonate; chloroformic acid ethyl ester; sodium hydrogencarbonate; sodium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; In tetrahydrofuran; methanol; dichloromethane; toluene; xylene; Petroleum ether; benzene; 3.1: intramolecular Diels-Alder reactiom / 13.1: Dieckmann condensation;
DOI:10.1021/ja0581346