{(triphos)RhH(μ-H)2HRh(triphos)}

Base Information

Chemical Name:{(triphos)RhH(μ-H)2HRh(triphos)}
CAS No.:116863-68-4
Molecular Formula:C₈₂H₈₂P₆Rh₂
Molecular Weight:1459.21
Hs Code.:

Synonyms:{(triphos)RhH(μ-H)2HRh(triphos)}

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Chemical Property of {(triphos)RhH(μ-H)2HRh(triphos)}

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Technology Process of {(triphos)RhH(μ-H)2HRh(triphos)}

There total 2 articles about {(triphos)RhH(μ-H)2HRh(triphos)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 100333-94-6
(triphos)RhH₃

: 116863-68-4
{(triphos)RhH(μ-H)2HRh(triphos)}

Guidance literature:: In tetrahydrofuran; Rh complex was refluxed in THF for 30 min, crystals ppt., soln. was cooled to room temp.; crystals filtered and washed with n-pentane/THF 3:1; elem. anal.;

Reference yield: 87.0%

: 104103-47-1
{(triphos)Rh(μ-H)3Rh(triphos)}BPh4

: 116863-68-4
{(triphos)RhH(μ-H)2HRh(triphos)}

Guidance literature:: With LiHB(C₂H₅)3; In tetrahydrofuran; to a suspension of Rh complex in THF was added soln. of LiHBEt3 in THF, solid dissolved to red soln.; addn. of few drops of EtOH caused pptn. of liver-red crystals; crystals filtered and washed with n-pentane/THF 3:1;

Reference yield: 62.0%

: 116863-68-4
{(triphos)RhH(μ-H)2HRh(triphos)}

: 143-66-8
sodium tetraphenyl borate

: 105736-81-0
{(triphos)RhH(μ-H)2HRh(triphos)}(BPh4)2

Guidance literature:: With O₂; In tetrahydrofuran; N,N-dimethyl-formamide; mixt. of Rh complex and NaBPh4 in THF/DMF (2:1) was stirred in air for 2 h, solid dissolved to give a red soln. Addn. of n-butanol (N2) gave orange crystalls.;