1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene

Base Information

Chemical Name:1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene
CAS No.:692204-98-1
Molecular Formula:C₅₇H₅₆Br₂ClIO₇
Molecular Weight:1175.23
Hs Code.:

1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene

Synonyms:1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene

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Chemical Property of 1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene

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Technology Process of 1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene

There total 18 articles about 1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 692204-93-6
{3-{3-(4-bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-4-iodo-phenyl}-methanol

: 692204-98-1
1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene

Guidance literature:: With N-Bromosuccinimide; triphenylphosphine; In tetrahydrofuran; at 20 ℃;
DOI:10.1021/jo049878p

Reference yield:

: 4142-98-7
ethyl 3,5-dihydroxybenzoate

: 692204-98-1
1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene

Guidance literature:: Multi-step reaction with 6 steps

1: 24 percent / N-iodosuccinimide / acetonitrile / 8 h

2: 31 percent / pyridine / CH₂Cl₂ / 6 h

3: potassium carbonate; 18-crown-6 / tetrahydrofuran / 12 h / Heating

4: borane-dimethyl sulfide complex / tetrahydrofuran / 8 h / Heating

5: 90 percent / potassium carbonate; 18-crown-6 / acetone / 12 h / Heating

6: 85 percent / triphenylphosphine; N-bromosuccinimide / tetrahydrofuran / 20 °C

With pyridine; N-Bromosuccinimide; N-iodo-succinimide; 18-crown-6 ether; dimethylsulfide borane complex; potassium carbonate; triphenylphosphine; In tetrahydrofuran; dichloromethane; acetone; acetonitrile;
DOI:10.1021/jo049878p

Reference yield:

: 18880-00-7
1-(bromomethyl)-4-(1,1-dimethylethyl)benzene

: 692204-98-1
1-{3-(4-Bromo-benzyloxy)-5-[2-(2-methyl-benzyloxy)-ethoxy]-benzyloxy}-5-bromomethyl-3-[3-(4-tert-butyl-benzyloxy)-5-(3-chloro-benzyloxymethyl)-benzyloxy]-2-iodo-benzene

Guidance literature:: Multi-step reaction with 8 steps

1: potassium carbonate; 18-crown-6 / tetrahydrofuran / 8 h / Heating

2: 1.96 g / sodium hydride / tetrahydrofuran / 1 h / 20 °C

3: 90 percent / borane-dimethyl sulfide complex / tetrahydrofuran / 8 h / Heating

4: 92 percent / triphenylphosphine; N-bromosuccinimide / tetrahydrofuran / 20 °C

5: potassium carbonate; 18-crown-6 / tetrahydrofuran / 12 h / Heating

6: borane-dimethyl sulfide complex / tetrahydrofuran / 8 h / Heating

7: 90 percent / potassium carbonate; 18-crown-6 / acetone / 12 h / Heating

8: 85 percent / triphenylphosphine; N-bromosuccinimide / tetrahydrofuran / 20 °C

With N-Bromosuccinimide; 18-crown-6 ether; dimethylsulfide borane complex; sodium hydride; potassium carbonate; triphenylphosphine; In tetrahydrofuran; acetone;
DOI:10.1021/jo049878p