((2E,6E)-9-(3-bromophenyl)-2,6-dimethylnona-2,6-dienyloxy)triisopropylsilane

Base Information

• Chemical Name: ((2E,6E)-9-(3-bromophenyl)-2,6-dimethylnona-2,6-dienyloxy)triisopropylsilane
• CAS No.: 1028386-37-9
• Molecular Formula: C₂₆H₄₃BrOSi
• Molecular Weight: 479.616

Synonyms:((2E,6E)-9-(3-bromophenyl)-2,6-dimethylnona-2,6-dienyloxy)triisopropylsilane

Chemical Property of ((2E,6E)-9-(3-bromophenyl)-2,6-dimethylnona-2,6-dienyloxy)triisopropylsilane

Chemical Property:

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Technology Process of ((2E,6E)-9-(3-bromophenyl)-2,6-dimethylnona-2,6-dienyloxy)triisopropylsilane

There total 1 articles about ((2E,6E)-9-(3-bromophenyl)-2,6-dimethylnona-2,6-dienyloxy)triisopropylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

triisopropylsilyl chloride (13154-24-0) + C17H23BrO → ((2E,6E)-9-(3-bromophenyl)-2,6-dimethylnona-2,6-dienyloxy)triisopropylsilane (1028386-37-9)

Guidance literature:

With 1H-imidazole; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1021/ol800499p

Reference yield: 30.0%

(4S,6S)-4,6-dimethyl-2-phenyl-1,3-dioxane (926892-40-2) + ((2E,6E)-9-(3-bromophenyl)-2,6-dimethylnona-2,6-dienyloxy)triisopropylsilane (1028386-37-9) → (1S,3aS,3bR,9bS,11aS)-7-bromo-3a,9b-dimethyl-1-phenyl-1,3,3a,3b,4,5,9b,10,11,11a-decahydrophenanthro[2,1-c]furan (1028386-40-4) + (2S,4S)-4-((7-bromo-1,4a-dimethyl-1-((triisopropylsilyloxy)methyl)-1,2,3,4,4a,9,10,10a-octahydrophenanthren-2-yl)(phenyl)methoxy)pentan-2-ol + (2S,4S)-4-((R)-((1S,2S,4aS,10aR)-7-bromo-1,4a-dimethyl-1-((triisopropylsilyloxy)methyl)-1,2,3,4,4a,9,10,10a-octahydrophenanthren-2-yl)(phenyl)methoxy)pentan-2-ol (1028386-35-7) + (2R,4R)-4-((S)-((1R,2R,4aR,10aS)-7-bromo-1,4a-dimethyl-1-((triisopropylsilyloxy)methyl)-1,2,3,4,4a,9,10,10a-octahydrophenanthren-2-yl)(phenyl)methoxy)pentan-2-ol

Guidance literature:

With tin(IV) chloride; In dichloromethane; at -78 - -70 ℃; optical yield given as %ee;

DOI:10.1021/ol800499p

upstream raw materials:

triisopropylsilyl chloride

Downstream raw materials:

(1S,3aS,3bR,9bS,11aS)-7-bromo-3a,9b-dimethyl-1-phenyl-1,3,3a,3b,4,5,9b,10,11,11a-decahydrophenanthro[2,1-c]furan

(2S,4S)-4-((R)-((1S,2S,4aS,10aR)-7-bromo-1,4a-dimethyl-1-((triisopropylsilyloxy)methyl)-1,2,3,4,4a,9,10,10a-octahydrophenanthren-2-yl)(phenyl)methoxy)pentan-2-ol

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