(1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol

Base Information

Chemical Name:(1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol
CAS No.:870119-22-5
Molecular Formula:C₂₆H₄₆O₄Sn
Molecular Weight:541.359
Hs Code.:

Synonyms:(1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol

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Chemical Property of (1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol

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Technology Process of (1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol

There total 1 articles about (1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 870119-31-6
(E)-(3-(methoxymethoxy)prop-2-ene-1,2-diyl)bis(tributyl)stannane

: 86544-37-8
(S)-α-methoxyphenylacetaldehyde

: 870119-22-5
(1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol

: C₆H₅CHOCH₃CHOHCHOCH₂OCH₃CCH₂Sn(C₄H₉)3

Guidance literature:: With magnesium bromide; In dichloromethane; Ar atm.; CH2Cl2, -78°C, 2 equiv of MgBr2*O(C2H5)2, 6 h; diasteromeric mixture in overall yield of 81%; diastereomeric ratio of >95:5;
DOI:10.1021/ja054201k

Reference yield:

: 870119-22-5
(1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol

: (1S,2S,3S)-1-Methoxy-1-phenyl-pent-4-ene-2,3-diol

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; at 50 ℃; for 3h;
DOI:10.1021/ja054201k

Reference yield:

: 870119-22-5
(1S,2R,3R)-1-methoxy-3-(methoxymethoxy)-1-phenyl-4-(tributylstannyl)pent-4-en-2-ol

: (4S,5S)-4-((S)-methoxyphenylmethyl)-2,2-dimethyl-5-vinyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 2 steps

1: aq. HCl / tetrahydrofuran / 3 h / 50 °C

2: camphorsulfonic acid / 12 h / 22 °C

With hydrogenchloride; camphor-10-sulfonic acid; In tetrahydrofuran;
DOI:10.1021/ja054201k