(E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene

Base Information

Chemical Name:(E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene
CAS No.:868528-14-7
Molecular Formula:C₂₅H₄₇N₃O₆S₃Si₂
Molecular Weight:638.034
Hs Code.:

Synonyms:(E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene

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Chemical Property of (E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene

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Technology Process of (E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene

There total 3 articles about (E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 868528-12-5
N-[(E)-4-chloro-2-butenyl]-N-(tert-butyloxycarbonyl)(2-trimethylsilylethyl)sulfonamide

: 868528-14-7
(E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / potassium carbonate / acetonitrile / 19 h / Heating

2: 97 percent / trifluoroacetic acid / CH₂Cl₂ / 48 h / 20 °C

With potassium carbonate; trifluoroacetic acid; In dichloromethane; acetonitrile;
DOI:10.1016/j.tet.2005.08.013

Reference yield:

: 125486-96-6
2-(trimethylsilyl)ethanesulfonamide

: 868528-14-7
(E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / DMAP; Et₃N / CH₂Cl₂ / 20 °C

2: 79 percent / potassium carbonate / acetonitrile / 6 h / Heating

3: 79 percent / potassium carbonate / acetonitrile / 19 h / Heating

4: 97 percent / trifluoroacetic acid / CH₂Cl₂ / 48 h / 20 °C

With dmap; potassium carbonate; triethylamine; trifluoroacetic acid; In dichloromethane; acetonitrile;
DOI:10.1016/j.tet.2005.08.013

Reference yield:

: 145387-82-2
N-(tert-butyloxycarbonyl)(2-trimethylsilylethyl)sulfonamide

: 868528-14-7
(E,E)-1,11-bis[(2-trimethylsilylethyl)sulfonyl]-6-(p-tolylsulfonyl)-1,6,11-triazaundeca-3,8-diene

Guidance literature:: Multi-step reaction with 3 steps

1: 79 percent / potassium carbonate / acetonitrile / 6 h / Heating

2: 79 percent / potassium carbonate / acetonitrile / 19 h / Heating

3: 97 percent / trifluoroacetic acid / CH₂Cl₂ / 48 h / 20 °C

With potassium carbonate; trifluoroacetic acid; In dichloromethane; acetonitrile;
DOI:10.1016/j.tet.2005.08.013