Naphthalen-1-ylmethyl-hydrazine

Base Information

• Chemical Name: Naphthalen-1-ylmethyl-hydrazine
• CAS No.: 51421-38-6
• Molecular Formula: C11H12N2
• Molecular Weight: 172.23
• Hs Code.: 2928000090
• DSSTox Substance ID: DTXSID201303592
• Mol file: 51421-38-6.mol

Synonyms:NAPHTHALEN-1-YLMETHYL-HYDRAZINE;51421-38-6;[(naphthalen-1-yl)methyl]hydrazine;(naphthalen-1-ylmethyl)hydrazine;naphthalen-1-ylmethylhydrazine;a-naphthylmethylhydrazine;(1-Naphthalenylmethyl)hydrazine;SCHEMBL2655761;DTXSID201303592;AKOS000134317;MCULE-2103344839;AS-83821

Chemical Property of Naphthalen-1-ylmethyl-hydrazine

Chemical Property:

• PSA: 38.05000
• LogP: 2.89430
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 172.100048391
• Heavy Atom Count: 13
• Complexity: 158

Purity/Quality:

98% ^*data from raw suppliers

Naphthalen-1-ylmethyl-hydrazine 95 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC=C2CNN

Technology Process of Naphthalen-1-ylmethyl-hydrazine

There total 3 articles about Naphthalen-1-ylmethyl-hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N'-(naphthalen-1-yl)methylhydrazinocarboxylic acid tert-butyl ester (1032-78-6) → naphthyl(1-methylhydrazine) (51421-38-6)

Guidance literature:

With hydrogenchloride;

DOI:10.1021/jo01013a001

Reference yield:

1-Chloromethylnaphthalene (86-52-2) → naphthyl(1-methylhydrazine) (51421-38-6)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N

2: HCl

With hydrogenchloride; triethylamine;

DOI:10.1021/jo01013a001

Reference yield:

→ naphthyl(1-methylhydrazine) (51421-38-6)

Guidance literature:

1-Chlormethyl-naphthalin, 98percentig.Hydrazin*H2O (Ueberschuss, Erhitzen);

upstream raw materials:

N'-(naphthalen-1-yl)methylhydrazinocarboxylic acid tert-butyl ester

1-Chloromethylnaphthalene