[3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane

Base Information

Chemical Name:[3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane
CAS No.:617705-39-2
Molecular Formula:C₂₀H₃₅IO₂Si
Molecular Weight:462.487
Hs Code.:

[3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-<i>tert</i>-butyl-dimethyl-silane

Synonyms:[3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane

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Chemical Property of [3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane

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Technology Process of [3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane

There total 2 articles about [3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 617705-50-7
methanesulfonic acid 5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentyl ester

: 617705-39-2
[3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane

Guidance literature:: With sodium hydrogencarbonate; sodium iodide; In acetone; for 3h; Heating;
DOI:10.1016/S0040-4020(03)00916-5

Reference yield:

: 224968-25-6
5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4,4-dimethyl-pentan-1-ol

: 617705-39-2
[3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / Et₃N; DMAP / tetrahydrofuran / 3 h / 0 °C

2: 84 mg / NaI; NaHCO₃ / acetone / 3 h / Heating

With dmap; sodium hydrogencarbonate; triethylamine; sodium iodide; In tetrahydrofuran; acetone;
DOI:10.1016/S0040-4020(03)00916-5

Reference yield: 37.0%

: 617705-28-9
2-[(E)-4-((4S,5R)-5-Formyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-en-1-ynyl]-oxazole-4-carboxylic acid ethyl ester

: 617705-39-2
[3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane

: 2-((E)-4-{(4S,5S)-5-[(Z)-(S)-6-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5,5-dimethyl-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-but-3-en-1-ynyl)-oxazole-4-carboxylic acid ethyl ester

Guidance literature:: [3-benzyloxy-1-(2-iodo-ethyl)-2,2-dimethyl-propoxy]-tert-butyl-dimethyl-silane; With N-ethyl-N,N-diisopropylamine; triphenylphosphine; at 90 ℃; for 18h;

2-[(E)-4-((4S,5R)-5-Formyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-en-1-ynyl]-oxazole-4-carboxylic acid ethyl ester; With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium hexamethyldisilazane; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1016/S0040-4020(03)00916-5